Version 1.5
Regulation (EC) No 1907/2006
1 - Product and Company Information
Product Name TETRAETHYLDIALUMINOXANE, 1.0M SOLUTION
I N TOLUENE
2 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Reacts violently with water. Spontaneously flammable in air. Toxic
by inhalation, in contact with skin and if swallowed.
3 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
TETRAETHYLDIALUMINOXANE, 1.0M 1069-83-6 None None
SOLUTION INTOLUENE
Formula C8H20Al2O
Molecular Weight 186,2100 AMU
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
5 - Fire Fighting Measures
CONDITIONS OF FLAMMABILITY
Catches fire if exposed to air.
EXTINGUISHING MEDIA
Suitable: Carbon dioxide, dry chemical powder, or appropriate
foam.
Unsuitable: Do not use water.
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SPECIAL RISKS
Specific Hazard(s): Pyrophoric material. Vapor may travel
considerable distance to source of ignition and flash back.
Emits toxic fumes under fire conditions.
Explosion Hazards: Vapor may travel considerable distance to
source of ignition and flash back. Container explosion may occur
under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
SPECIFIC METHOD(S) OF FIRE FIGHTING
Use water spray to cool fire-exposed containers.
6 - Accidental Release Measures
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area. Shut off all sources of ignition.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Cover with an activated carbon adsorbent, take up and place in
closed containers. Transport outdoors. Ventilate area and wash
spill site after material pickup is complete.
7 - Handling and Storage
HANDLING
Directions for Safe Handling: Do not breathe vapor. Do not get
in eyes, on skin, on clothing. Avoid prolonged or repeated
exposure.
STORAGE
Conditions of Storage: Keep tightly closed. Store in a cool dry
place.
Incompatible Materials: Do not allow contact with water
8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Safety shower and eye bath. Use only in a chemical fume hood.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling. Wash contaminated clothing before
reuse.
PERSONAL PROTECTIVE EQUIPMENT
Special Protective Measures: Wear appropriate government approved
respirator, chemical-resistant gloves, safety goggles, other
protective clothing.
9 - Physical and Chemical Properties
pH N/A
BP/BP Range 111,000 °C
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MP/MP Range N/A
Flash Point N/A
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure N/A
SG/Density 0,8600 g/cm3
Partition Coefficient N/A
Viscosity N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A
10 - Stability and Reactivity
STABILITY
Conditions of Instability: Air.
Reactions to Avoid: Reacts violently with:
Materials to Avoid: Oxidizing agents, Water.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Aluminum, Aluminum oxide.
11 - Toxicological Information
SIGNS AND SYMPTOMS OF EXPOSURE
Exposure to and/or consumption of alcohol may increase toxic
effects. Inhalation studies on toluene have demonstrated the
development of inflammatory and ulcerous lesions of the penis,
prepuce, and scrotum in animals. Lung irritation, chest pain,
and edema which may be fatal. Exposure can cause: Symptoms of
exposure may include burning sensation, coughing, wheezing,
laryngitis, shortness of breath, headache, nausea, and vomiting.
ROUTE OF EXPOSURE
Multiple Routes: High concentrations are extremely destructive
to tissues of the mucous membranes and upper respiratory tract,
eyes, and skin. Harmful if swallowed, inhaled, or absorbed
through skin.
TARGET ORGAN INFORMATION
Bladder. Kidneys. Liver. Brain.
CONDITIONS AGGRAVATED BY EXPOSURE
May cause nervous system disturbances.
12 - Ecological Information
No data available.
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13 - Disposal Considerations
SUBSTANCE DISPOSAL
Burn in a chemical incinerator equipped with an afterburner and
scrubber but exert extra care in igniting as this material is
highly flammable. Observe all federal, state, and local
environmental regulations.
14 - Transport Information
RID/ADR
UN#: 3394
Class: 4.2
PG: I
Subrisk: 4.3
Proper Shipping Name: Organometallic substance,
liquid, pyrophoric, water-reactive
IMDG
UN#: 3394
Class: 4.2
PG: I
Subrisk: 4.3
Proper Shipping Name: Organometallic substance,
liquid, pyrophoric, water-reactive
Marine Pollutant: No
Severe Marine Pollutant: No
Technical Name: Required
IATA
UN#: 3394
Class: 4.2
PG: I
Subrisk: 4.3
Proper Shipping Name: Organometallic substance,
liquid, pyrophoric, water-reactive
Inhalation Packing Group I: No
Technical Name: Required
15 - Regulatory Information
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: F-T
Highly Flammable. Toxic.
R-PHRASES: 14-17-23/24/25
Reacts violently with water. Spontaneously flammable in air.
Toxic by inhalation, in contact with skin and if swallowed.
S-PHRASES: 16-26-28-36/37/39-45
Keep away from sources of ignition - no smoking. In case of
contact with eyes, rinse immediately with plenty of water and
seek medical advice. After contact with skin, wash immediately
with plenty of water. Wear suitable protective clothing,
gloves, and eye/face protection. In case of accident or if you
feel unwell, seek medical advice immediately (show the label
where possible).
Caution: Substance not yet fully tested (EU).
16 - Other Information
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WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2010 Co. License granted to make
unlimitedpaper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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SECTION 16 - ADDITIONAL INFORMATION
N/A
