碳酸铷 [584-09-8]

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学
  • 表征图谱

碳酸铷 [584-09-8] 基本信息

中文名称:
碳酸铷 [584-09-8] 
中文别名:
碳酸铷;
Potassium carbonate hemihydrate;
Potassiumcarbonate;
Dipotassium carbonate;
Carbonic acid, dipotassium salt;
Carbonate Of Potash;
Salt of tartar;
alt of wormwood;
Pearl ash;
Potassium carbonate,anhydrous;
Heavy potassium carbonate;
Potassium carbonate;
Cyclohexanone, 2-methyl-;
(2R)-2-methylcyclohexanone;
(2S)-2-methylcyclohexanone;
2-Methylcyclohexanone;
2-merkaptobenzimidazol;
2-Thiobenzimidazole;
2-Thiol benzimidazole;
Aniti 
英文名称:
Carbonic acid, rubidiumsalt (1:2)
英文别名:
Rubidium carbonate;
rubidium(1+),carbonate 
CAS No.:
584-09-8
分 子 式:
CH2O3.2Rb
分 子 量:
230.94
精确分子量:
229.80800
PSA:
63.19000
MDL:
MFCD00011188
EINECS:
209-530-9
InChI:
InChI=1/CH2O3.2Rb/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2
危险品标志:
风险术语:
R36/37/38   
安全术语:
S26;S37/39
分子结构式:
SDS:
查看

碳酸铷 [584-09-8] 制备方法及用途

制备方法

用途:特殊玻璃用作分析试剂,也用于合成其他铷盐。 制取金属铷和各种铷盐的原料、特种玻璃的生产、微型高能电池和晶体闪烁计数器。

合成制备方法

 

用途简介

用途

用途:特殊玻璃

 

用作分析试剂,也用于合成其他铷盐。

碳酸铷 [584-09-8] 物化性质

外观与性状:
无色单斜晶体,吸湿的
熔点:
837 °C
沸点:
333.6ºC at 760mmHg
闪点:
169.8ºC
水溶解性:
soluble
存储条件/存储方法:

贮存:

将密器密封,储存密封的主藏器内,并放在阴凉, 干爽的位置。

稳定性相关:

稳定性和反应性:

要避免的物料:氧化物,水分,潮湿,酸,空气。

要分解的产品:一氧化碳和二氧化碳。

其它信息:

白色结晶粉末,易潮解,具有强碱性,溶于水,不溶于醇。溶点:837℃

碳酸铷 [584-09-8] 安全信息

WGK_Germany:
2
德国有关水污染物质的分类清单
危险类别码:
R36/37/38
安全说明:
S26-S36/37/39-S37/39
RTECS号:
FG0650000
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:
:
危险标志:
Xi:Irritant;

碳酸铷 [584-09-8] 毒理性

毒理学数据:

急性毒性:

与分类相关的LD/LC50值:

口腔   LD50     2625mg/kg(rat)

生态数据:

三、生态学数据:

1、其它有害作用:该物质对环境可能有危害,对水体应给予特别注意。

碳酸铷 [584-09-8] MSDS

Name: Rubidium Carbonate 99% Material Safety Data Sheet
Synonym: Dirubidium Carbonate; Dirubidium Monocarbonate; Carbonic Acid, Dirubidium Salt
CAS: 584-09-8
Section 1 - Chemical Product   MSDS Name:Rubidium Carbonate 99% Material Safety Data Sheet
Synonym:Dirubidium Carbonate; Dirubidium Monocarbonate; Carbonic Acid, Dirubidium Salt

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
584-09-8 Rubidium Carbonate 99.0 209-530-9
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Hygroscopic (absorbs moisture from the air).Air sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. May cause central, peripheral, and autonomic nervous system effects. Peripheral nervous system effects are characterized by muscular weakness, paresthesias, numbness in limbs, unsteadiness and difficulties in walking and standing.
Inhalation:
May cause respiratory tract irritation. May cause effects similar to those described for ingestion.
Chronic:
Effects may be delayed.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Non-combustible, substance itself does not burn but may decompose upon heating to produce irritating, corrosive and/or toxic fumes.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
Place under an inert atmosphere.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Handle under an inert atmosphere. Store protected from air.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Do not expose to air. Store protected from moisture. Store under an inert atmosphere.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 584-09-8: Russia: 0.5 mg/m3 TWA Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Powder
Color: white
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 837 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: CO3Rb2
Molecular Weight: 230.95

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures. May decompose on exposure to air.
Conditions to Avoid:
Incompatible materials, exposure to air, exposure to moist air or water.
Incompatibilities with Other Materials:
Air, moisture, strong acids, strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, rubidium.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 584-09-8: FG0650000 LD50/LC50:
CAS# 584-09-8: Oral, rat: LD50 = 2625 mg/kg.
Carcinogenicity:
Rubidium Carbonate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 37/39 Wear suitable gloves and eye/face
protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 584-09-8: 1
Canada
CAS# 584-09-8 is listed on Canada's NDSL List.
CAS# 584-09-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 584-09-8 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

碳酸铷 [584-09-8] 分子结构与计算化学数据

计算化学数据

四、计算化学数据:

2、   氢键供体数量:0

3、   氢键受体数量:3

4、   可旋转化学键数量:0

5、   拓扑分子极性表面积(TPSA):63.2

6、   重原子数量:6

7、   表面电荷:0

8、   复杂度:18.8

9、   同位素原子数量:0

10、   确定原子立构中心数量:0

11、   不确定原子立构中心数量:0

12、   确定化学键立构中心数量:0

13、   不确定化学键立构中心数量:0

14、   共价键单元数量:3

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