色酚AS-BO

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品

色酚AS-BO 基本信息

中文名称:
色酚AS-BO 
中文别名:
N-萘-1-基-3-羟基萘-2-甲酰胺;
2-羟基-3-萘甲酸-1-萘酰胺;
色酚AS-BO;
纳夫妥AS-BO;
3-羟基-N-(1-萘基)-2-萘甲酰胺;
冰染偶氮组分4 
英文名称:
2-Naphthalenecarboxamide,3-hydroxy-N-1-naphthalenyl-
英文别名:
3-Hydroxy-N-naphthalen-1-ylnaphthalene-2-carboxamide;
3-Hydroxy-[2]naphthoesaeure-[1]naphthylamid;
naphthol ASSW;
3-Hydroxy-N-(1-naphthyl)-2-naphthamide;
Naphtoelan BO;
Azonaphtol AN;
3-Hydroxy-N-(naphthyl-(1))-naphthamid-(2);
3-hydroxy-[2]naphthoic acid-[1]naphthylamide;
Naphthol AS-BO;
Naphthoide BO;
2-Hydroxy-3-naphthoic Acid 1-Naphthylamide;
Dragonthol BO;
Acco Naphthol AS-BO;
Brenthol AN;
Naphtanilide BO;
Solunaptol ANL;
Azoic Coupling Component 4;
Cibanaphthol RN;
3-HYDROXY-NAPHTHALENE-2-CARBOXYLIC ACID NAPHTHALEN-1-YLAMIDE;
3-hydroxy-naphthalene-2-carboxylic acid naphthalen-1-ylamide 
CAS No.:
132-68-3
分 子 式:

C21H15NO2

分 子 量:
313.35
精确分子量:
313.11000
PSA:
49.33000
EINECS:
205-075-5
InChI:
InChI=1/C21H15NO2/c23-20-13-16-8-2-1-7-15(16)12-18(20)21(24)22-19-11-5-9-14-6-3-4-10-17(14)19/h1-13,23H,(H,22,24)
危险品标志:

 

风险术语:

 

安全术语:

 

分子结构式:
SDS:
查看

色酚AS-BO 制备方法及用途

制备方法

以 2,3-酸和 1-萘胺为原料,首先将 2,3-酸制成钠盐,然后在三氯化磷存在下与 1-萘胺缩合,经中和、蒸馏、过滤、洗涤、干燥得成品。。在成盐锅中加入氯苯 4000-5000L、30%氢氧化钠 500L、2,3-酸 630kg (100%计)。升温脱水,至 134-135℃,蒸出液中透明无水为终点。料液体积约为 2800-3000L。将上述成盐溶液压入缩合锅中,冷却至 90℃时加入 1-萘胺 479kg (100%计),继续冷却至 67℃左右,于 2h 内均匀加入三氯化磷-氯苯混合液 (由 230kg 三氯化磷与无水氯苯配成的 55%-60%混合液)。加完后温度为 118-120℃,保温 2h。在蒸馏釜中加入水 1000L、30%氢氧化钠 330L,然后压入上述缩合液,搅拌 15min,控制 pH=8-8.5。然后通入直接蒸汽蒸氯苯,直至蒸出液澄清无氯苯为止。再加入 90℃以上的热水洗涤,至滤液澄清,脱水,干燥得成品约 960kg。

合成制备方法

生产方法简述

以2,3酸为原料,用氯苯与烧碱成盐、脱水,再与甲萘胺和三氯化磷缩合,而后经中和、蒸馏、过滤、洗涤及干燥而得。原料消耗(kg/t)2,3酸(100%) 660甲萘胺 500三氯化磷 250氯苯(98%) 173纯碱(98%) 500

用途简介

主要用作棉纤维染色、印花的打底剂,并用作有机颜料中间体,以及用于制造快色素。

用途

用途

主要用作棉纤维染色、印花的打底剂,并用作有机颜料中间体,以及用于制造快色素。

色酚AS-BO 物化性质

外观与性状:
淡浅黄色黄色粉末
密度:
1.333 g/cm3
熔点:
222~223℃
沸点:
479.3ºC at 760 mmHg
闪点:
243.6°C
折射率:
1.778
蒸汽压:
8.27E-10mmHg at 25°C
稳定性相关:

基本性质

该品为米色粉末。不溶于水和碳酸钠溶液,可溶于二甲苯。于氢氧化钠溶液中呈黄色。熔点为222-223℃

色酚AS-BO 安全信息

海关代码:
2924299090
RTECS号:
QJ1897300

色酚AS-BO 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QJ1897300
CHEMICAL NAME :
2-Naphthalenecarboxamide, 3-hydroxy-N-1-naphthalenyl-
CAS REGISTRY NUMBER :
132-68-3
BEILSTEIN REFERENCE NO. :
1824371
LAST UPDATED :
199701
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C21-H15-N-O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>12 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 33(10),57,1989
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
7320 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Behavioral - irritability Gastrointestinal - other changes
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 33(10),57,1989
TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>12 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 33(10),57,1989
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
5280 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Behavioral - irritability Gastrointestinal - other changes
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 33(10),57,1989
毒理学数据:

急性毒性数据:

大鼠经口LD>12mg/kg

大鼠腹腔LD507320mg/kg

小鼠经口LD>12mg/kg

小鼠腹腔LD505280mg/kg

色酚AS-BO MSDS

  3-Hydroxy-N-(1-naphthyl)-2-naphthamide      Revision number: 5    
  SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        3-Hydroxy-N-(1-naphthyl)-2-naphthamide    
    
  Revision number:        5    

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS        Not classified    
    Not classified
  HEALTH HAZARDS
  ENVIRONMENTAL HAZARDS        Not classified    
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols        None    
    No signal word
  Signal word
  Hazard statements        None    
    None
  Precautionary statements:

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance    
  Components:        3-Hydroxy-N-(1-naphthyl)-2-naphthamide    
  Percent:        ....    
  CAS Number:        132-68-3    
  Synonyms:        2-Hydroxy-3-naphthoic Acid 1-Naphthylamide , Naphthol AS-BO , Azoic Coupling    
    Component 4
    C21H15NO2
  Chemical Formula:

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.    
    Get medical advice/attention if you feel unwell.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Rinse skin with    
    water/shower. If skin irritation or rash occurs: Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present    
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Get medical advice/attention if you feel unwell. Rinse mouth.    
    A rescuer should wear personal protective equipment, such as rubber gloves and air-
  Protection of first-aiders:
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.    
  media:
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
  from the chemical:        generate poisonous fume.    
  3-Hydroxy-N-(1-naphthyl)-2-naphthamide

Section 5. FIRE-FIGHTING MEASURES
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.    
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
    Use personal protective equipment. Keep people away from and upwind of spill/leak.
  Personal precautions,
  protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
  emergency procedures: roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
  containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
  up: appropriate laws and regulations.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
    Handling is performed in a well ventilated place. Wear suitable protective equipment.
  Technical measures:
    Prevent dispersion of dust. Wash hands and face thoroughly after handling.
    Use a local exhaust if dust or aerosol will be generated.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.    
    Store away from incompatible materials such as oxidizing agents.
  Packaging material:        Comply with laws.    

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
    Install a closed system or local exhaust as possible so that workers should not be
  Engineering controls:
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Dust respirator. Follow local and national regulations.
  Hand protection:        Protective gloves.    
  Eye protection:        Safety glasses. A face-shield, if the situation requires.    
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Solid    
  Form:        Crystal- Powder    
  Colour:        White - Slightly pale yellow red    
  Odour:        No data available    
  pH: No data available
  Melting point/freezing point:No data available
    No data available
  Boiling point/range:
  Flash point:        No data available    
  Flammability or explosive
  limits:
    No data available
  Lower:
  Upper:        No data available    
    No data available
  Relative density:
  Solubility(ies):
    No data available
  [Water]
  [Other solvents]        No data available    
  3-Hydroxy-N-(1-naphthyl)-2-naphthamide

Section 10. STABILITY AND REACTIVITY
  Chemical stability:        Stable under proper conditions.    
  Possibility of hazardous No special reactivity has been reported.
  reactions:
  Incompatible materials: Oxidizing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx)
  products:

Section 11. TOXICOLOGICAL INFORMATION
    ipr-rat LD50:7320 mg/kg
  Acute Toxicity:
    orl-rat LD:>12 g/kg
  Skin corrosion/irritation: No data available
  Serious eye        No data available    
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available    
    No data available
  NTP =
  Reproductive toxicity:        No data available    
    QJ1897300
  RTECS Number:

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available    
  Crustacea:        No data available    
  Algae:        No data available    
  Persistence / degradability: No data available
  Bioaccumulative        No data available    
  potential(BCF):
  Mobility in soil
  Log Pow:        No data available    
  Soil adsorption (Koc):        No data available    
  Henry's Law        No data available    
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
    Observe all federal, state and local regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        Does not correspond to the classification standard of the United Nations    
  UN-No:        Not listed    

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.
  3-Hydroxy-N-(1-naphthyl)-2-naphthamide


SECTION 16 - ADDITIONAL INFORMATION
N/A

色酚AS-BO 海关数据

中国海关编码:2924299090

概述:
2924299090. 其他环酰胺(包括环氨基甲酸酯)(包括其衍生物以及他们的盐). 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素:
品名, 成分含量, 用途, 包装
摘要/Summary:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

色酚AS-BO 分子结构与计算化学数据

分子结构数据

 

五、分子性质数据:

1   摩尔折射率98.39

2   摩尔体积m3/mol):234.9

3   等张比容90.2K):669.5

4   表面张力3.0 dyne/cm):65.9

5   极化率0.5 10-24cm3):39.00

计算化学数据

1.疏水参数计算参考值(XlogP):5.5

2.氢键供体数量:2

3.氢键受体数量:2

4.可旋转化学键数量:2

5.互变异构体数量:9

6.拓扑分子极性表面积49.3

7.重原子数量:24

8.表面电荷:0

9.复杂度:451

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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