偏锑酸钠

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

偏锑酸钠 基本信息

中文名称:
偏锑酸钠 
中文别名:
锑酸钠;
三水锑酸钠;
偏锑酸钠;
三水锑酸钠, 98+%;
锑酸钠三水合物 
英文名称:
Antimonate (SbO31-),sodium (1:1)
英文别名:
Sodium antimonate;
Trisodium antimonate;
Sodiumantimonate,min.;
Natriumantimonat;
Antimonate,sodium;
SODIUM METAANTIMONATE 
CAS No.:
15432-85-6
分 子 式:
Na.O3Sb
分 子 量:
192.73
精确分子量:
191.87800
PSA:
57.20000
MDL:
MFCD00058775
EINECS:
239-444-7
危险品标志:
风险术语:
R20/22   
安全术语:
S22
分子结构式:
SDS:
查看

偏锑酸钠 制备方法及用途

制备方法

用作不透明填料、搪瓷的乳白剂及铁皮、钢板的抗酸漆 用作玻璃澄清剂,也可用作阻燃增效剂

合成制备方法

偏锑酸钠 物化性质

外观与性状:
白色粉末
密度:
3.7 g/mL at 25 °C(lit.)
熔点:
>375 °C(lit.)
水溶解性:
slightly soluble
存储条件/存储方法:

应贮存于通风、干燥的库房中。

稳定性相关:

偏锑酸钠 安全信息

包装等级:
III
风险类别:
6.1
危险类别码:
R20/22
安全说明:
S22-S61
安全标志:
S22:不要吸入粉尘。
S61:避免排放到环境中。参考专门的说明/安全数据表。
危险标志:
Xn:Harmful;

偏锑酸钠 毒理性

毒理学数据:

急性中毒表现为呼吸道、消化道及皮肤的刺激作用。慢性中毒影响体内物质代谢,神经系统,心肌。锑化合物进入胃,口腔内有金属味,可引起流涎、恶心、呕吐、腹泻和腹痛;长期吸入锑尘,可导致肺部疾病。

生态数据:

对水体是危害的,即使小量产品不能接触地下水,水道或污水系统,未经政府许可勿将材料排入周围环境。

偏锑酸钠 MSDS

Name: Sodium antimonate, 96+% Material Safety Data Sheet
Synonym: None reported
CAS: 15432-85-6
Section 1 - Chemical Product MSDS Name: Sodium antimonate, 96+% Material Safety Data Sheet
Synonym: None reported
SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
15432-85-6 Sodium antimonate 99.5% 239-444-7
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW The toxicological properties of this material have not been fully investigated. Potential Health Effects
Eye:
No information regarding eye irritation and other potential effects was found.
Skin:
No information regarding skin irritation and other potential effects was found.
Ingestion:
The toxicological properties of this substance have not been fully investigated.
Inhalation:
The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.
SECTION 4 - FIRST AID MEASURES
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:


SECTION 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.
SECTION 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Avoid contact with skin and eyes. Avoid ingestion and inhalation. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 15432-85-6: Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: white
Odor: Odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: slightly soluble in water
Specific Gravity/Density:
Molecular Formula: NaO3Sb
Molecular Weight: 192.74
SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stability unknown.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Not available.
Hazardous Polymerization: Has not been reported
SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 15432-85-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Sodium antimonate - Not listed by ACGIH, IARC, or NTP.
SECTION 12 - ECOLOGICAL INFORMATION
SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations.
SECTION 14 - TRANSPORT INFORMATION IATA
Shipping Name: ANTIMONY COMPOUND, INORGANIC, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 1549
Packing Group: III IMO
Shipping Name: ANTIMONY COMPOUND, INORGANIC, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 1549
Packing Group: III RID/ADR
Shipping Name: ANTIMONY COMPOUND, INORGANIC, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 1549
Packing group: III
SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases: S 22 Do not breathe dust. WGK (Water Danger/Protection) CAS# 15432-85-6: No information available. Canada CAS# 15432-85-6 is listed on Canada's DSL List. CAS# 15432-85-6 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 15432-85-6 is listed on the TSCA inventory.
SECTION 16 - ADDITIONAL INFORMATION
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages.

SECTION 16 - ADDITIONAL INFORMATION
N/A

偏锑酸钠 分子结构与计算化学数据

分子结构数据


计算化学数据

1、 疏水参数计算参考值(XlogP):

2、 氢键供体数量:0

3、 氢键受体数量:4

4、 可旋转化学键数量:0

5、 互变异构体数量:

6、 拓扑分子极性表面积(TPSA):86.3

7、 重原子数量:8

8、 表面电荷:0

9、 复杂度:36.8

10、 同位素原子数量:0

11、 确定原子立构中心数量:0

12、 不确定原子立构中心数量:0

13、 确定化学键立构中心数量:0

14、 不确定化学键立构中心数量:0

15、 共价键单元数量:4

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