1-萘酚-2-磺酸钾

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学
  • 表征图谱

1-萘酚-2-磺酸钾 基本信息

中文名称:
1-萘酚-2-磺酸钾 
中文别名:
1-萘酚-2-磺酸钾盐;
1-萘酚-2-磺酸钾 
英文名称:
potassium 1-hydroxynaphthalenesulphonate
英文别名:
1-NAPHTHOL-2-SULFONIC ACID POTASSIUM SALT;
1-hydroxy-2-naphthalenesulfonicacimonopotassiumsalt;
potassium salt of 1-naphthol-2-sulfonate;
potassium 1-napthol-2-sulfonate;
1-HYDROXY-2-NAPHTHALENESULFONIC ACID POTASSIUM SALT;
POTASSIUM 1-NAPHTHOL-2-SULFONATE;
potassium 1-hydroxynaphthalenesulphonate;
1-Naphthol-2-sulfonic acid potassium salt,pract.;
1-HYDROXYNAPHTHALENE-2-SULFONIC ACID POTASSIUM SALT 
CAS No.:
832-49-5
分 子 式:
C10H8O4S.K
分 子 量:
262.32
精确分子量:
261.97000
PSA:
85.81000
MDL:
MFCD00041825
EINECS:
212-617-4
InChI:
InChI=1/C10H8O4S/c11-10-8-4-2-1-3-7(8)5-6-9(10)15(12,13)14/h1-6,11H,(H,12,13,14)/p-1
风险术语:
R36/37/38
安全术语:
S24/25
分子结构式:
SDS:
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1-萘酚-2-磺酸钾 物化性质

熔点:
89-93 °C(lit.)
存储条件/存储方法:

保持容器密封,储存在阴凉,干燥的地方 

稳定性相关:

常温常压下稳定,避免强氧化剂接触

其它信息:

1.       性状:未确定

2.       密度(g/mL,25/4):未确定

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):未确定

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:未确定

1-萘酚-2-磺酸钾 安全信息

危险类别码:
R36/37/38:Irritating to eyes, respiratory system and skin .
安全说明:
S24/25
安全标志:
S24/25:防止皮肤和眼睛接触。

1-萘酚-2-磺酸钾 毒理性

生态数据:

对水是稍微有害的,不要让未稀释或大量的产品接触地下水,水道或者污水系统,若无政府许可,勿将材料排入周围环境

1-萘酚-2-磺酸钾 MSDS

Name: 1-Naphthol-2-sulfonic acid potassium salt (pract) 92% (uv-vis) Material Safety Data Sheet
Synonym: 2-Naphthalenesulfonic acid, 1-hydroxy-, monopotassium sal
CAS: 832-49-5
Section 1 - Chemical Product   MSDS Name:1-Naphthol-2-sulfonic acid potassium salt (pract) 92% (uv-vis) Material Safety Data Sheet
Synonym:2-Naphthalenesulfonic acid, 1-hydroxy-, monopotassium sal

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
832-49-5 1-Naphthol-2-sulfonic acid potassium s 92 212-617-4
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 832-49-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Crystalline powder
Color: brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C10H7KO4S
Molecular Weight: 262.32

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 832-49-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Naphthol-2-sulfonic acid potassium salt - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 832-49-5: No information available.
Canada
CAS# 832-49-5 is listed on Canada's DSL List.
CAS# 832-49-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 832-49-5 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

1-萘酚-2-磺酸钾 分子结构与计算化学数据

计算化学数据

1、   氢键供体数量:1

2、   氢键受体数量:4

3、   可旋转化学键数量:1

4、   互变异构体数量:3

5、   拓扑分子极性表面积(TPSA):77.4

6、   重原子数量:16

7、   表面电荷:0

8、   复杂度:324

9、   同位素原子数量:0

10、   确定原子立构中心数量:0

11、   不确定原子立构中心数量:0

12、   确定化学键立构中心数量:0

13、   不确定化学键立构中心数量:0

14、   共价键单元数量:2

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