D-炔丙基甘氨酸

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学

D-炔丙基甘氨酸 基本信息

中文名称:
D-炔丙基甘氨酸 
中文别名:
D-炔丙基甘氨酸;
D-Propargylglycine Propargyl-D-glycine H-Propargyl-D-Gly-OH H-D-Gly(propargyl)-OH 
英文名称:
4-Pentynoic acid,2-amino-,(2R)-
英文别名:
(2R)-2-aminopent-4-ynoic acid;
AmbotzHAA6490;
propargylglycine,(R)-isomer;
(R)-2-Aminopent-4-ynoic acid;
C5H7NO2;
(R)-2-amino-4-pentynoic acid;
(R)-propargylglycine;
2-Amino-pent-4-ynoic acid;
2-(R)-propargylglycine;
(R)-alpha-Propargylglycine 
CAS No.:
23235-03-2
分 子 式:

C5H7NO2

分 子 量:
113.11
精确分子量:
113.04800
PSA:
49.33000
MDL:
MFCD00237407
InChI:
The Key: DGYHPLMPMRKMPD-SCSAIBSYSA-N
危险品标志:

 

风险术语:

 

安全术语:

 

分子结构式:
SDS:
查看

D-炔丙基甘氨酸 制备方法及用途

合成制备方法


用途


D-炔丙基甘氨酸 物化性质

密度:
1.209g/cm3
沸点:
272.1ºC at 760 mmHg
闪点:
118.3ºC
折射率:
1.512
蒸汽压:
0.00174mmHg at 25°C
存储条件/存储方法:


稳定性相关:


其它信息:

1. 性状:未确定

2. 密度(g/mL,25/4):未确定

3. 相对蒸汽密度(g/mL,空气=1未确定

4. 熔点(ºC):未确定

5. 沸点(ºC,常压):未确定

6. 沸点(ºC,5.2kPa): 未确定

7. 折射率: 未确定

8. 闪点(ºC): 未确定

9. 比旋光度(º): 未确定

10. 自燃点或引燃温度(ºC): 未确定

11. 蒸气压(kPa,25ºC): 未确定

12. 饱和蒸气压(kPa,60ºC): 未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC): 未确定

15. 临界压力(KPa): 未确定

16. 油水(辛醇/水)分配系数的对数值: 未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V): 未确定

19. 溶解性:未确定


D-炔丙基甘氨酸 安全信息

海关代码:
2922499990

D-炔丙基甘氨酸 毒理性

毒理学数据:


生态数据:


D-炔丙基甘氨酸 MSDS

  Material Safety Data Sheet

Section 1. Identification of the substance
    Product Name:      D-Propargylglycine    
    Synonyms:

Section 2. Hazards identification
    Harmful by inhalation, in contact with skin, and if swallowed.

Section 3. Composition/information on ingredients.
    Ingredient name:        D-Propargylglycine    
    CAS number:        23235-03-2    

Section 4. First aid measures
    Skin contact:        Immediately wash skin with copious amounts of water for at least 15 minutes while removing    
    contaminated clothing and shoes. If irritation persists, seek medical attention.
    Eye contact:        Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate    
    flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
    attention.
    Inhalation:        Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.    
    Ingestion:        Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.    

Section 5. Fire fighting measures
    In the event of a fire involving this material, alone or in combination with other materials, use dry
    powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
    should be worn.

Section 6. Accidental release measures
    Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
    standards.
    Respiratory precaution:        Wear approved mask/respirator    
    Hand precaution:        Wear suitable gloves/gauntlets    
    Skin protection:        Wear suitable protective clothing    
    Eye protection:        Wear suitable eye protection    
    Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
    for disposal. See section 12.
    Environmental precautions: Do not allow material to enter drains or water courses.

Section 7. Handling and storage
    Handling:        This product should be handled only by, or under the close supervision of, those properly qualified    
    in the handling and use of potentially hazardous chemicals, who should take into account the fire,
    health and chemical hazard data given on this sheet.
    Store in closed vessels.
    Storage:

Section 8. Exposure Controls / Personal protection
    Engineering Controls: Use only in a chemical fume hood.
    Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
    General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section 9. Physical and chemical properties
    Appearance:        Not specified    
    Boiling point:        No data    
    No data
    Melting point:
    Flash point:        No data    
    Density:        No data    
    Molecular formula:        C5H7NO2    
    Molecular weight:        113.1    

Section 10. Stability and reactivity
    Conditions to avoid: Heat, flames and sparks.
    Materials to avoid: Oxidizing agents.
    Possible hazardous combustion products: Carbon monoxide, nitrogen oxides.

Section 11. Toxicological information
    No data.

Section 12. Ecological information
    No data.

Section 13. Disposal consideration
    Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
    disposal authority, in accordance with national and regional regulations.

Section 14. Transportation information
    Non-harzardous for air and ground transportation.

Section 15. Regulatory information
    No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
    302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
    Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A

D-炔丙基甘氨酸 海关数据

中国海关编码:2922499990

概述:
2922499990 其他氨基酸及其酯及它们的盐(含有一种以上含氧基的除外). 增值税率:17.0% 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 最惠国关税:6.5% 普通关税:30.0%
申报要素:
品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装
监管条件:
A.入境货物通关单B.出境货物通关单
检验检疫:
P.进境动植物、动植物产品检疫Q.出境动植物、动植物产品检疫R.进口食品卫生监督检验S.出口食品卫生监督检验M.进口商品检验N.出口商品检验
摘要/Summary:
HS:2922499990 other amino-acids, other than those containing more than one kind of oxygen function, and their esters; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%

D-炔丙基甘氨酸 分子结构与计算化学数据

分子结构数据

五、分子性质数据:

1、   摩尔折射率:28.09

2、   摩尔体积(cm3/mol):128.9

3、   等张比容(90.2K)93.5

4、   表面张力(dyne/cm)258.2

5、   极化率(10-24cm3)11.13

计算化学数据

1.疏水参数计算参考值(XlogP):-2.8

2.氢键供体数量:2

3.氢键受体数量:3

4.可旋转化学键数量:2

5.互变异构体数量:无

6.拓扑分子极性表面积63.3

7.重原子数量:8

8.表面电荷:0

9.复杂度:133

10.同位素原子数量:0

11.确定原子立构中心数量:1

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

推荐供应商更多供应商>>

上海吉至生化科技有限公司

产品介绍:
产品名称:(R)-2-氨基戊-4-炔酸 Cas号:23235-03-2 纯度:98% 包装信息:1gea,250mgea,25gea,5gea 价格:59.0元 - 4,121.0元
联系方式:
联系人:江珊 电话:021-57520831 手机:15316869680

上海楚肽生物科技有限公司

产品介绍:
产品名称:H-D-Pra-OH Cas号:23235-03-2 纯度:>98% 包装信息:100kg,1kg,100g,10g,1g 价格:洽谈
联系方式:
联系人:吴经理 电话:021-50673982 手机:17321195801

上海瀚思化工有限公司

产品介绍:
产品名称:(R)-2-氨基戊-4-炔酸 Cas号:23235-03-2 纯度:98% 包装信息:250mg 价格:134.4元
联系方式:
联系人:张 电话:021-64806089 手机:18049821080

江苏海翔化工有限公司

产品介绍:
产品名称:D-炔丙基甘氨酸 Cas号:23235-03-2 纯度:98%-99% 包装信息:2kg 价格:洽谈
联系方式:
联系人:周逸 电话:+86-519-82331677;82311677;80191677 手机:13915811283

徐州市万特化工有限公司

产品介绍:
产品名称:D-炔丙基甘氨酸 Cas号:23235-03-2 纯度:98%-99% 包装信息:2kg 价格:洽谈
联系方式:
联系人:贺文珠 电话:0516-87762960 手机:

海盐利晖化工塑料有限公司

产品介绍:
产品名称:D-炔丙基甘氨酸 Cas号:23235-03-2 纯度:98%-99% 包装信息:2kg 价格:洽谈
联系方式:
联系人:程汉忠 电话:86-573-6766402 手机:

SIEGFRIED

产品介绍:
产品名称:D-炔丙基甘氨酸 Cas号:23235-03-2 纯度:98%-99% 包装信息:2kg 价格:洽谈
联系方式:
联系人: 电话:+41627461111 手机: