氟钛酸钾

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学
  • 表征图谱

氟钛酸钾 基本信息

中文名称:
氟钛酸钾 
中文别名:
氟钛酸钾;
氟化钛钾;
(OC-6-11)六氟合钛酸(2-)钾;
氟化鉀鈦 
英文名称:
Titanate(2-),hexafluoro-, potassium (1:2), (OC-6-11)-
英文别名:
Potassium hexafluorotitanate;
Postassium fluorotitanate;
fluotitanatedepotassium;
POTASSIUM FLUOROTITANATE;
Dipotassium hexafluorotitanate Titanium potassium hexafluoride;
CATALYST PTF;
Dipotassium hexafluorotitanateTitanium potassium hexafluoride;
TITANIUM POTASSIUM FLUORIDE;
Dikaliumhexafluorotitanat;
POTASSIUM TITANIUM FLUORIDE 
CAS No.:
16919-27-0
分 子 式:
F6K2Ti
分 子 量:
240.04
精确分子量:
239.86600
PSA:
0.00000
MDL:
MFCD00011380
EINECS:
240-969-9
InChI:
InChI=1/FH.K.Ti/h1H;;/q;+1;+4/p-1
危险品标志:
HarmfulXn
风险术语:
R22;R41;R43;
安全术语:
S26;S36/37/39;
分子结构式:
SDS:
查看

氟钛酸钾 制备方法及用途

制备方法

合成法 氢氟酸与偏钛酸作用生成氟钛酸,然后再用氢氧化钾中和制取氟钛酸钾。其

合成制备方法

合成法  氢氟酸与偏钛酸作用生成氟钛酸,然后再用氢氧化钾中和制取氟钛酸钾。其

            

用途简介

用于聚丙烯合成的催化剂,制铝、钛、硼合金。

用途

1.用作分析试剂,也用于钛酸和金属钛的制造

2.是金属磷化表调剂的组成成分,用作聚丙烯合成催化剂等

3.用作合成聚丙烯的催化剂。还用于铝钛硼合金制造、铝加工及轻金属冶炼的添加剂。


氟钛酸钾 物化性质

外观与性状:
白色结晶粉末
密度:
3.01
熔点:
780℃
沸点:
235-237°C
闪点:
235-237°C
存储条件/存储方法:

1.常温密闭避光,通风干燥,储存于阴凉干燥通风库房中。

2.运输时应防雨受潮,防止碰撞。

3.远离火种、热源。严禁与氧化剂、食用化学品等混装混运。

稳定性相关:

常温常压下稳定

避免的物料:氧化物
其它信息:

1. 性状:白色片状结晶

2. 密度(g/mL,25/4):3.012

3. 熔点(ºC):780

4. 沸点(ºC,常压):235-237

5. 闪点(ºC): 235-23719. 溶解性:溶于热水,微溶于冷水和无机酸。

6.溶解性:溶于热水,微溶于冷水和无机酸。

氟钛酸钾 安全信息

包装等级:
III
风险类别:
6.1
WGK_Germany:
2
德国有关水污染物质的分类清单
危险类别码:
R22;R41;R43
安全说明:
S26-S36/37/39
RTECS号:
TT1575000
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:
危险标志:
Xn:Harmful;

氟钛酸钾 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TT1575000
CHEMICAL NAME :
Potassium hexafluorotitanate
CAS REGISTRY NUMBER :
16919-27-0
LAST UPDATED :
199701
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
F6-Ti.2K
MOLECULAR WEIGHT :
240.10
WISWESSER LINE NOTATION :
KA2 TI-F6

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Amphibian - frog
DOSE/DURATION :
360 mg/kg
REFERENCE :
CRSBAW Comptes Rendus des Seances de la Societe de Biologie et de Ses Filiales. (SPPIF, B.P.22, F-41353 Vineuil, France) V.1- 1849- Volume(issue)/page/year: 124,133,1937 *** REVIEWS *** TOXICOLOGY REVIEW AMSSAQ Acta Medica Scandinavica, Supplement. (Almqvist & Wiksell, POB 45150, S-10430 Stockholm, Sweden) No.1-730, 1921-88. Volume(issue)/page/year: 400,5,1963 *** U.S. STANDARDS AND REGULATIONS *** OSHA PEL (Gen Indu):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO FLUORIDES, INORGANIC-air:10H TWA 2.5 mg(F)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X2929 No. of Facilities: 63 (estimated) No. of Industries: 6 No. of Occupations: 13 No. of Employees: 8704 (estimated) No. of Female Employees: 40 (estimated)
毒理学数据:

急性毒性:皮下注射:360 mg/kg。

生态数据:

通常对水体是稍微有害的,不要将未稀释或大量产品接触地下水,水道或污水系统,未经政府许可勿将材料排入周围环境。

氟钛酸钾 MSDS


Section 1. Chemical Product and Company Identification
    Potassium titanium fluoride
    Common Name/
    Trade Name
    Manufacturer
    Commercial Name(s)
    Synonym
    Chemical Name
    Chemical Family
    Potassium titanium fluoride

Section 4. First Aid Measures
    Eye Contact        Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at    
    least 15 minutes. Get medical attention.
    Skin Contact        Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.    
    Serious Skin Contact        Not available.    
    Inhalation        If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get    
    medical attention.
    Serious Inhalation        Not available.    
    Ingestion        Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an    
    unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
    clothing such as a collar, tie, belt or waistband.
    Serious Ingestion        Not available.    

Section 5. Fire and Explosion Data
    Flammability of the Product Non-flammable.
    Auto-Ignition Temperature Not applicable.
    Flash Points        Not applicable.    
    Flammable Limits        Not applicable.    
    Products of Combustion        Not available.    
    Fire Hazards in Presence of Not applicable.
    Various Substances
    Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
    Risks of explosion of the product in presence of static discharge: Not available.
    of Various Substances
    Not applicable.
    Fire Fighting Media
    and Instructions
    When heated to decomposition it emits highly toxic fumes of potassium oxides, fluorine, titanium/titanium oxides.
    Special Remarks on
    Fire Hazards
    Special Remarks on Explosion Not available.
    Hazards

Section 6. Accidental Release Measures
    Small Spill        Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by    
    spreading water on the contaminated surface and dispose of according to local and regional authority
    requirements.
    Large Spill        Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water    
    on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not
    present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
    Potassium titanium fluoride

Section 7. Handling and Storage
    Precautions        Do not breathe dust. Avoid contact with eyes. Never add water to this product. Wear suitable protective    
    clothing. If ingested, seek medical advice immediately and show the container or the label. Store in an
    appropriate container.
    Storage        Keep container tightly closed. Keep container in a cool, well-ventilated area.    

Section 8. Exposure Controls/Personal Protection
    Engineering Controls        Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below    
    recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
    airborne contaminants below the exposure limit.
    Personal Protection        Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.    
    Gloves.
    Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
    a Large Spill        to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist    
    BEFORE handling this product.
    Exposure Limits        TWA: 2.5 (mg(F)/m3) from OSHA (PEL) [United States]    
    TWA: 2.5 (mg/(F)m3) from ACGIH (TLV) [United States]
    Consult local authorities for acceptable exposure limits.

Section 9. Physical and Chemical Properties
    Physical state and appearance Solid.        Odor        Not available.    
    Not available.
    Taste
    Molecular Weight        239.84 g/mole    
    Not available.
    Color
    Not available.
    pH (1% soln/water)
    Boiling Point        Not available.    
    Not available.
    Melting Point
    Critical Temperature        Not available.    
    Specific Gravity        Not available.    
    Vapor Pressure        Not applicable.    
    Vapor Density        Not available.    
    Not available.
    Volatility
    Odor Threshold        Not available.    
    Water/Oil Dist. Coeff.        Not available.    
    Ionicity (in Water)        Not available.    
    Dispersion Properties        Not available.    
    Solubility        Not available.    

Section 10. Stability and Reactivity Data
    Stability        The product is stable.    
    Instability Temperature        Not available.    
    Conditions of Instability        Incompatible materials    
    Incompatibility with various Reactive with oxidizing agents.
    substances
    Potassium titanium fluoride
    Corrosivity        Not available.    
    Special Remarks on        Not available.    
    Reactivity
    Special Remarks on        Not available.    
    Corrosivity
    Polymerization        Will not occur.    

Section 11. Toxicological Information
    Routes of Entry        Inhalation. Ingestion.    
    Toxicity to Animals        LD50: Not available.    
    LC50: Not available.
    Chronic Effects on Humans Not available.
    Other Toxic Effects on        Hazardous in case of ingestion.    
    Humans
    Slightly hazardous in case of skin contact (irritant), of inhalation.
    Special Remarks on        Not available.    
    Toxicity to Animals
    Special Remarks on        Not available.    
    Chronic Effects on Humans
    Special Remarks on other        Acute Potential Health Effects:    
    Toxic Effects on Humans        Skin: May cause skin irritation.    
    Eyes: Causes eye irritation.
    Inhalation: May cause respiratory tract irritation.
    Ingestion: May be harmful if swallowed.

Section 12. Ecological Information
    Ecotoxicity        Not available.    
    Not available.
    BOD5 and COD
    Possibly hazardous short term degradation products are not likely. However, long term degradation products may
    Products of Biodegradation
    arise.
    Toxicity of the Products        The product itself and its products of degradation are not toxic.    
    of Biodegradation
    Special Remarks on the        Not available.    
    Products of Biodegradation

Section 13. Disposal Considerations
    Waste Disposal        Waste must be disposed of in accordance with federal, state and local environmental    
    control regulations.

Section 14. Transport Information
    DOT Classification        Not a DOT controlled material (United States).    
    Not applicable.
    Identification
    Not applicable.
    Special Provisions for
    Transport
    Potassium titanium fluoride
    DOT (Pictograms)

Section 15. Other Regulatory Information and Pictograms
    TSCA 8(b) inventory: Potassium titanium fluoride
    Federal and State
    Regulations
    California        California prop. 65: This product contains the following ingredients for which the State of California has found    
    to cause cancer which would require a warning under the statute: No products were found.
    Proposition 65
    Warnings
    California prop. 65: This product contains the following ingredients for which the State of California has found
    to cause birth defects which would require a warning under the statute: No products were found.
    Other Regulations        EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No.    
    240-969-9).
    Canada: Listed on Canadian Domestic Substance List (DSL).
    China: Listed on National Inventory.
    Japan: Listed on National Inventory (ENCS).
    Korea: Listed on National Inventory (KECI).
    Philippines: Listed on National Inventory (PICCS).
    Australia: Listed on AICS.
    Other Classifications        WHMIS (Canada) CLASS D-2B: Material causing other toxic effects (TOXIC).    
    DSCL (EEC)        R22- Harmful if swallowed.        S26- In case of contact with eyes, rinse    
    R36- Irritating to eyes.        immediately with plenty of water and seek    
    R43- May cause sensitization by skin        medical advice.    
    contact.        S46- If swallowed, seek medical advice    
    immediately and show this container or label.
    Health Hazard
    HMIS (U.S.A.)        2 National Fire Protection    
    0 Flammability
    0 Association (U.S.A.)
    Fire Hazard
    2 0 Reactivity
    Health
    Reactivity
    0
    Specific hazard
    Personal Protection
    E
    WHMIS (Canada)
    (Pictograms)
    DSCL (Europe)
    (Pictograms)
    TDG (Canada)
    (Pictograms)
    ADR (Europe)
    (Pictograms)
    Protective Equipment
    Potassium titanium fluoride
    Gloves.
    Lab coat.
    Dust respirator. Be sure to use an
    approved/certified respirator or
    equivalent.


SECTION 16 - ADDITIONAL INFORMATION
N/A

氟钛酸钾 分子结构与计算化学数据

计算化学数据

1、 疏水参数计算参考值(XlogP:

2、 氢键供体数量:0

3、 氢键受体数量:6

4、 可旋转化学键数量:0

5、 互变异构体数量:

6、 拓扑分子极性表面积(TPSA;0

7、 重原子数量:9

8、 表面电荷:0

9、 复杂度:0

10、 同位素原子数量:0

11、 确定原子立构中心数量:0

12、 不确定原子立构中心数量:0

13、 确定化学键立构中心数量:0

14、 不确定化学键立构中心数量:0

15、 :共价键单元数量:9

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