Section 1. Chemical Product and Company Identification
Nickel Sulfamate, Solution
Common Name/
Trade Name
Manufacturer
Commercial Name(s)
Synonym
Chemical Name
Chemical Family
Nickel Sulfamate, Solution
Section 4. First Aid Measures
Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Cold water may be used. Get medical attention immediately.
Skin Contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before
reuse. Thoroughly clean shoes before reuse. Get medical attention.
Serious Skin Contact Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate
medical attention.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Serious Inhalation Not available.
Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
clothing such as a collar, tie, belt or waistband.
Serious Ingestion Not available.
Section 5. Fire and Explosion Data
Flammability of the Product Non-flammable.
Auto-Ignition Temperature Not applicable.
Flash Points Not applicable.
Flammable Limits Not applicable.
Products of Combustion Not available.
Fire Hazards in Presence of Not applicable.
Various Substances
Explosion Hazards in Presence Non-explosive in presence of open flames and sparks, of shocks.
of Various Substances
Fire Fighting Media Not applicable.
and Instructions
Special Remarks on Not available.
Fire Hazards
Special Remarks on Explosion Not available.
Hazards
Section 6. Accidental Release Measures
Small Spill Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal
container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and
regional authority requirements.
Large Spill Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by
spreading water on the contaminated surface and allow to evacuate through the sanitary system.
Nickel Sulfamate, Solution
Section 7. Handling and Storage
Precautions Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. If ingested, seek
medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing
agents.
Storage Keep container tightly closed. Keep container in a cool, well-ventilated area.
Section 8. Exposure Controls/Personal Protection
Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value.
Personal Protection Safety glasses. Lab coat. Gloves.
Respiratory protection is not necessary for normal handling. Adequate general (room) ventilation or local exhaust
(fume hood) is sufficient. Use a vapor respirator under conditions where exposure to the substance is apparent
(e.g. generation of high concentrations of mist or vapor, inadequate ventilation, development of respiratory tract
irritation), and engineering controls are not feasible. Be sure to use an approved/certified respirator or equivalent.
Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a
a Large Spill specialist BEFORE handling this product.
Exposure Limits Not available.
Section 9. Physical and Chemical Properties
Physical state and appearance Liquid. Odor Odorless.
Not available.
Taste
Molecular Weight Not applicable.
Green. Bluish-Green. Clear (Dark.)
Color
pH (1% soln/water) Not available.
Boiling Point >104.44°C (220°F)
Melting Point Not available.
Critical Temperature Not available.
Specific Gravity Not available.
Not applicable.
Vapor Pressure
Vapor Density Not available.
Not available.
Volatility
Odor Threshold Not available.
Water/Oil Dist. Coeff. Not available.
Ionicity (in Water) Not available.
Dispersion Properties Not available.
Solubility Soluble in cold water.
Section 10. Stability and Reactivity Data
Stability The product is stable.
Instability Temperature Not available.
Conditions of Instability Incompatible materials
Incompatibility with various Reactive with oxidizing agents.
substances
Nickel Sulfamate, Solution
Corrosivity Non-corrosive in presence of glass.
Special Remarks on Not available.
Reactivity
Special Remarks on Not available.
Corrosivity
Polymerization Will not occur.
Section 11. Toxicological Information
Routes of Entry Skin contact. Eye contact.
Toxicity to Animals LD50: Not available.
LC50: Not available.
Chronic Effects on Humans Not available.
Other Toxic Effects on Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Humans
Special Remarks on Not available.
Toxicity to Animals
Special Remarks on May cause cancer (Nickel Sulfamate)
Chronic Effects on Humans
Special Remarks on other Acute Potential Health Effects:
Toxic Effects on Humans Skin: Can cause skin irritation.
Eyes: Can cause eye irritation.
Inhalaiton: May cause respiratory tract irritation.
Ingestion: May be harmful if swallowed.
Chronic Potential Health Effects:
Skin: Prolonged or repeated skin contact may cause allergic skin reaction (allergic contact dermatitis).
Section 12. Ecological Information
Ecotoxicity Not available.
BOD5 and COD Not available.
Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may
arise.
Toxicity of the Products The products of degradation are less toxic than the product itself.
of Biodegradation
Not available.
Special Remarks on the
Products of Biodegradation
Section 13. Disposal Considerations
Waste must be disposed of in accordance with federal, state and local environmental
Waste Disposal
control regulations.
Nickel Sulfamate, Solution
Section 14. Transport Information
DOT Classification Not a DOT controlled material (United States).
Identification Not applicable.
Not applicable.
Special Provisions for
Transport
DOT (Pictograms)
Section 15. Other Regulatory Information and Pictograms
California prop. 65: This product contains the following ingredients for which the State of California has found to
Federal and State
cause cancer, birth defects or other reproductive harm, which would require a warning under the statute: Nickel
Regulations
sulfamate (listed as Nickel compounds)
California prop. 65: This product contains the following ingredients for which the State of California has found to
cause cancer which would require a warning under the statute: Nickel sulfamate (Listed as Nickel compounds)
SARA 313 toxic chemical notification and release reporting: Nickel sulfamate (Listed as Nickel compounds)
California prop. 65: This product contains the following ingredients for which the State of California has found
California
Proposition 65 to cause cancer which would require a warning under the statute: Nickel sulfamate (Listed as Nickel
Warnings compounds)
California prop. 65: This product contains the following ingredients for which the State of California has found
to cause birth defects which would require a warning under the statute: No products were found.
Other Regulations For Nickel Sulfamate (CAS no. 13770-89-3):
EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No.
237-396-1).
Canada: Listed on Canadian Domestic Substance List (DSL).
China: Not listed on National Inventory.
Japan: Listed on National Inventory (ENCS).
Korea: Listed on National Inventory (KECI).
Philippines: Listed on National Inventory (PICCS).
Australia: Listed on AICS.
Other Classifications WHMIS (Canada) CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
Class D-2B: Material causing other toxic effects (TOXIC).
DSCL (EEC) R22- Harmful if swallowed. S26- In case of contact with eyes, rinse
R40- Limited evidence of a immediately with plenty of water and seek
carcinogenic effect. medical advice.
R43- May cause sensitization by skin S28- After contact with skin, wash immediately
contact. with plenty of water.
S36/37/39- Wear suitable protective clothing,
gloves and eye/face protection.
S46- If swallowed, seek medical advice
immediately and show this container or label.
Health Hazard
HMIS (U.S.A.) 1 National Fire Protection
0 Flammability
0 Association (U.S.A.)
Fire Hazard
1 0 Reactivity
Health
Reactivity
0
Specific hazard
Personal Protection
E
WHMIS (Canada)
(Pictograms)
Nickel Sulfamate, Solution
DSCL (Europe)
(Pictograms)
TDG (Canada)
(Pictograms)
ADR (Europe)
(Pictograms)
Protective Equipment
Gloves.
Lab coat.
Dust respirator. Be sure to use an
approved/certified respirator or
equivalent. Wear appropriate respirator
when ventilation is inadequate.
SECTION 16 - ADDITIONAL INFORMATION
N/A