1-甲基靛红

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品

1-甲基靛红 基本信息

中文名称:
1-甲基靛红 
中文别名:
1-甲基靛红;
1-甲基吲哚-2,3-二酮;
1-甲基-2,3-吲哚二酮;
N-甲基靛紅 
英文名称:
1-methylisatin
英文别名:
1-methylindole-2,3-dione;
N-methylindole-2,3-dione;
1-Methyl-indole-2,3-dione;
N-methylindol-2,3-dione;
1-Methylisatin;
1-Methyl-2,3-indolinedione;
1-Methylindole-2,3-dione;
1-methylindoline-2,3-dione;
OL-57;
N-Methylindoline-2,3-dione;
1-methylindole-2,3(1H)-dione;
1-methylisatin;
1-methyl-2,3-indolinedione;
N-Methylisatin;
INDOLE-2,3-DIONE,1-METHYL;
1-Methyl-1H-indole-2,3-dione;
1H-Indole-2,3-dione,1-methyl 
CAS No.:
2058-74-4
分 子 式:

C9H7NO2

分 子 量:
161.16
精确分子量:
161.04800
PSA:
37.38000
MDL:
MFCD00005812
EINECS:
218-164-9
BRN:
128280
InChI:
InChI=1/C9H7NO2/c1-10-7-5-3-2-4-6(7)8(11)9(10)12/h2-5H,1H3
危险品标志:

ToxicT;

风险术语:

R25;R41;R37/38

安全术语:

S24/25

分子结构式:
SDS:
查看

1-甲基靛红 物化性质

外观与性状:
橙色至褐色结晶粉末
密度:
1.314g/cm3
熔点:
130-133 °C(lit.)
沸点:
294.3ºC at 760mmHg
闪点:
137.4ºC
折射率:
1.607
蒸汽压:
0.00164mmHg at 25°C
存储条件/存储方法:

保持贮藏器密封、储存在阴凉、干燥的地方,确保工作间有良好的通风或排气装置

 

稳定性相关:

如果遵照规格使用和储存则不会分解,未有已知危险反应,避免氧化物

        

其它信息:

1.       性状:粉末

2.       密度(g/mL,25ºC):未确定

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):131-133

5.       沸点(ºC):未确定

6.       沸点(ºC5.5mmHg):未确定

7.       折射率:未确定

8.       闪点(°F):未确定

9.       比旋光度(ºF):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(kPa,20ºC):未确定

12.    饱和蒸气压(kPa,45ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:未确定

1-甲基靛红 安全信息

海关代码:
2933990090
WGK_Germany:
3
德国有关水污染物质的分类清单
危险类别码:
R25
安全说明:
S26-S39-S45
RTECS号:
NL7939000
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S39:佩戴眼/面防护装置。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
危险标志:
T: Toxic;

1-甲基靛红 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
NL7939000
CHEMICAL NAME :
Indole-2,3-dione, 1-methyl-
CAS REGISTRY NUMBER :
2058-74-4
BEILSTEIN REFERENCE NO. :
0128280
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C9-H7-N-O2
MOLECULAR WEIGHT :
161.17
WISWESSER LINE NOTATION :
T56 BNVVJ B1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
685 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
PCJOAU Pharmaceutical Chemistry Journal (English Translation). Translation of KHFZAN. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013) No.1- 1967- Volume(issue)/page/year: 15,858,1981
毒理学数据:

1、急性毒性:小鼠经腹腔LD50698mg/kg

生态数据:

对水是稍微有危害的不要让未稀释或大量的产品接触地下水、水道或者污水系统,若无政府许可,勿将材料排入周围环境。

1-甲基靛红 MSDS

Name: 1-Methylisatin 98% Material Safety Data Sheet
Synonym:
CAS: 2058-74-4
Section 1 - Chemical Product   MSDS Name:1-Methylisatin 98% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
2058-74-4 1-Methylisatin 98% 218-164-9
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 2058-74-4: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Crystalline powder
Color: orange to brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 129-133 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C9H7NO2
Molecular Weight: 161.16

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 2058-74-4: NL7939000 LD50/LC50:
Not available.
Carcinogenicity:
1-Methylisatin - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 2058-74-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 2058-74-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2058-74-4 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

1-甲基靛红 海关数据

中国海关编码:2933990090

概述:
2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途, 乌洛托品请注明外观, 6-己内酰胺请注明外观, 签约日期
摘要/Summary:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

1-甲基靛红 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:2

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积37.4

7.重原子数量:12

8.表面电荷:0

9.复杂度:237

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

推荐供应商更多供应商>>

山东默派生物科技有限公司

产品介绍:
产品名称:1-甲基靛红 Cas号:2058-74-4 纯度:99% 包装信息:1kg 价格:洽谈
联系方式:
联系人:张经理 电话:13070690626 手机:13070690626

湖北臻博化工有限公司

产品介绍:
产品名称:1-甲基靛红 Cas号:2058-74-4 纯度:98% 包装信息:200kg,25kg,1kg 价格:洽谈
联系方式:
联系人:张经理 电话:18071535998 手机:18071535998

湖北鑫鸣泰化学有限公司

产品介绍:
产品名称:1-甲基靛红 Cas号:2058-74-4 纯度:99% 包装信息:100kg,200kg 价格:1.0元 - 1.0元
联系方式:
联系人:黄 电话:027-50662354 手机:13264726139

上海瀚思化工有限公司

产品介绍:
产品名称:1-甲基靛红 Cas号:2058-74-4 纯度:97% 包装信息:25g 价格:1,714.0元
联系方式:
联系人:张 电话:021-64806089 手机:18049821080

合肥赛曼诺生物科技有限公司

产品介绍:
产品名称:1-甲基靛红 Cas号:2058-74-4 纯度:98%-99% 包装信息:2kg 价格:洽谈
联系方式:
联系人:周沐 电话:0551-65326643 手机:18156095617

杭州沿山化工有限公司

产品介绍:
产品名称:1-甲基靛红 Cas号:2058-74-4 纯度:98%-99% 包装信息:2kg 价格:洽谈
联系方式:
联系人:吴荣生 电话:0571-86897279 手机:13505814955

湖北鑫鸣泰化学有限公司

产品介绍:
产品名称:1-甲基靛红 Cas号:2058-74-4 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:黄经理 电话:027-51833411 手机:13237166274

北京中科拓展化学技术有限公司

产品介绍:
产品名称:1-甲基靛红 Cas号:2058-74-4 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:宋先生 电话:010-51600645 手机:

阿法埃莎(天津)化学有限公司

产品介绍:
产品名称:1-甲基靛红 Cas号:2058-74-4 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:张海滨 电话:800-810-6000 手机:

Wuhan GC Enterprise Company Limited

产品介绍:
产品名称:1-甲基靛红 Cas号:2058-74-4 纯度:98%-99% 包装信息:2kg 价格:洽谈
联系方式:
联系人: 电话:86-27-85483121 手机: