聚丙烯酸

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • MSDS

聚丙烯酸 基本信息

中文名称:
聚丙烯酸 
中文别名:
聚丙烯酸;
卡波姆;
羧基乙烯共聚物 
英文名称:
POLY(ACRYLIC ACID)
英文别名:
Carbomer;
POLY(ACRYLIC ACID) 
CAS No.:
9007-20-9
分 子 式:
(C3H4O2)n
分 子 量:
72.06270
精确分子量:
72.02110
PSA:
37.30000
EINECS:
202-415-4
风险术语:
45-46
分子结构式:
SDS:
查看

聚丙烯酸 制备方法及用途

制备方法

本品为丙烯酸键合烯丙基蔗糖或季戊四醇烯丙醚的高分子聚合物。卡波也称卡波姆(carbomer),是以季戊四醇等与丙烯酸交联得到的丙烯酸交联树脂,是一类非常重要的流变调节剂,中和后的卡波是优秀的凝胶基质,有增稠悬浮等重要用途,工艺简单,稳定性好,广泛应用于乳液、膏霜、凝胶中。

用途简介

聚丙烯酸 物化性质

密度:
1.063g/cm3
熔点:
12.5ºC
沸点:
141ºC
闪点:
61.6ºC
折射率:
n20/D 1.442

聚丙烯酸 安全信息

海关代码:
3906909090
危险类别码:
45-46
安全说明:
53-45
危险标志:
C: Corrosive;

聚丙烯酸 MSDS


Section 1. Chemical Product and Company Identification
    Carbomer 1342, 1622
    Common Name/
    Trade Name
    Manufacturer
    Commercial Name(s)
    Synonym
    Chemical Name
    Chemical Family
    Carbomer 1342, 1622

Section 4. First Aid Measures
    Eye Contact        Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at    
    least 15 minutes. Cold water may be used. Get medical attention if irritation occurs.
    Skin Contact        Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.    
    Cold water may be used.
    Serious Skin Contact        Not available.    
    Inhalation        If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get    
    medical attention.
    Serious Inhalation        Not available.    
    Ingestion        Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an    
    unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if
    symptoms appear.
    Serious Ingestion        Not available.    

Section 5. Fire and Explosion Data
    Flammability of the Product May be combustible at high temperature.
    Auto-Ignition Temperature 520°C (968°F)
    Flash Points        Not available.    
    Flammable Limits        Not available.    
    These products are carbon oxides (CO, CO2), phosphates.
    Products of Combustion
    Fire Hazards in Presence of Slightly flammable to flammable in presence of heat.
    Various Substances
    Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
    of Various Substances        Risks of explosion of the product in presence of static discharge: Not available.    
    Fire Fighting Media        SMALL FIRE: Use DRY chemical powder.    
    and Instructions        LARGE FIRE: Use water spray, fog or foam. Do not use water jet.    
    Special Remarks on        As with most organic solids, fire is possible at elevated temperatures.    
    Fire Hazards        Material in powder form, capable of creating a dust explosion.    
    Special Remarks on Explosion Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust
    Hazards        explosion hazard.    

Section 6. Accidental Release Measures
    Small Spill        Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by    
    spreading water on the contaminated surface and dispose of according to local and regional authority
    requirements.
    Large Spill
    Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water
    on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not
    present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
    Carbomer 1342, 1622

Section 7. Handling and Storage
    Precautions        Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not    
    ingest. Do not breathe dust. If ingested, seek medical advice immediately and show the container or the label.
    Storage        Keep container tightly closed. Keep container in a cool, well-ventilated area.    

Section 8. Exposure Controls/Personal Protection
    Engineering Controls        Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below    
    recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
    airborne contaminants below the exposure limit.
    Personal Protection
    Safety glasses. Lab coat. Dust respirator is ot normally required. Use a dust respirator if ventilation is not
    adequate and if handling of material (particularly in large quantities) creates visible dust clouds. Be sure to use an
    approved/certified respirator or equivalent. Gloves.
    Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
    a Large Spill        to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist    
    BEFORE handling this product.
    Exposure Limits        Not available.    

Section 9. Physical and Chemical Properties
    Physical state and appearance Solid.        Odor        Acetic acid. (Slight.)    
    Taste        Not available.    
    Molecular Weight        Not available.    
    White.
    Color
    2.5 - 3.0 [Acidic.]
    pH (1% soln/water)
    Boiling Point        Not available.    
    Not available.
    Melting Point
    Critical Temperature        Not available.    
    Specific Gravity        1.4 (Water = 1)    
    Vapor Pressure        Not applicable.    
    Vapor Density        Not available.    
    Volatility        Not available.    
    Odor Threshold        Not available.    
    Not available.
    Water/Oil Dist. Coeff.
    Ionicity (in Water)        Not available.    
    Dispersion Properties        See solubility in water.    
    Solubility        Easily soluble in cold water, hot water.    

Section 10. Stability and Reactivity Data
    Stability        The product is stable.    
    Not available.
    Instability Temperature
    Conditions of Instability        Excess heat, incompatible materials, dust generation.    
    Incompatibility with various        Reactive with alkalis.    
    substances
    Corrosivity        Non-corrosive in presence of glass.    
    Carbomer 1342, 1622
    Heat may be generated if polymer comes in contact with strong basic materials such as ammonia, sodium
    Special Remarks on
    Reactivity        hydroxide, postassium hydroxide or stronly basic amines.    
    Special Remarks on        Not available.    
    Corrosivity
    Polymerization        Will not occur.    

Section 11. Toxicological Information
    Routes of Entry        Dermal contact. Inhalation. Ingestion.    
    Toxicity to Animals        Acute oral toxicity (LD50): 2000 mg/kg [Guinea pig].    
    Acute dermal toxicity (LD50): 3000 mg/kg [Rabbit].
    Chronic Effects on Humans CARCINOGENIC EFFECTS: 3 (Not classifiable for human.) by IARC.
    May cause damage to the following organs: upper respiratory tract, skin, eyes.
    Other Toxic Effects on        Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.    
    Humans
    Special Remarks on        Not available.    
    Toxicity to Animals
    Special Remarks on        Not available.    
    Chronic Effects on Humans
    Special Remarks on other        Acute Potential Health Effects:    
    Toxic Effects on Humans        Skin: May cause skin irritation.    
    Eyes: Dust may cause irritation by mechanical action, not by chemical effect.
    Inhalation: Inhalation of dust may cause irritation by mechanical action, not by chemical effect. Symptoms may
    include coughing, mucous production, and shortness of breath
    Ingestion: Low hazard.
    Chronic Potential Health Effects:
    Skin: Prolonged or repeated skin contact may cause dermatits.
    Medical Conditions Aggravated by Exposure: Pre-existing respiratory diseases; pre-existing skin problems.
    I

Section 12. Ecological Information
    Ecotoxicity in water (LC50): 580 - 2000 mg/l 96 hours [Fish (Bluegill, Sunfish)]. 168 - 280 mg/l 96 hours
    Ecotoxicity
    [Daphnia (daphnia)].
    BOD5 and COD        Not available.    
    Possibly hazardous short term degradation products are not likely. However, long term degradation products may
    Products of Biodegradation
    arise.
    The product itself and its products of degradation are not toxic.
    Toxicity of the Products
    of Biodegradation
    Not available.
    Special Remarks on the
    Products of Biodegradation

Section 13. Disposal Considerations
    Waste Disposal        Waste must be disposed of in accordance with federal, state and local environmental    
    control regulations.
    Carbomer 1342, 1622

Section 14. Transport Information
    DOT Classification        Not a DOT controlled material (United States).    
    Identification        Not applicable.    
    Not applicable.
    Special Provisions for
    Transport
    DOT (Pictograms)

Section 15. Other Regulatory Information and Pictograms
    TSCA 8(b) inventory: Carbomer 1342, 1622
    Federal and State
    Regulations
    California        California prop. 65: This product contains the following ingredients for which the State of California has found    
    to cause cancer which would require a warning under the statute: No products were found.
    Proposition 65
    Warnings
    California prop. 65: This product contains the following ingredients for which the State of California has found
    to cause birth defects which would require a warning under the statute: No products were found.
    Other Regulations        Canada: Listed on Canadian Domestic Substance List (DSL).    
    Other Classifications        WHMIS (Canada) Not controlled under WHMIS (Canada).    
    DSCL (EEC)        This product is not classified according Not applicable.    
    to the EU regulations.
    Health Hazard
    HMIS (U.S.A.)        1 National Fire Protection    
    1 Flammability
    1 Association (U.S.A.)
    Fire Hazard
    1 0 Reactivity
    Health
    Reactivity
    0
    Specific hazard
    Personal Protection
    E
    WHMIS (Canada)
    (Pictograms)
    DSCL (Europe)
    (Pictograms)
    TDG (Canada)
    (Pictograms)
    ADR (Europe)
    (Pictograms)
    Carbomer 1342, 1622
    Protective Equipment
    Gloves.
    Lab coat.
    Dust respirator. Be sure to use an
    approved/certified respirator or
    equivalent.


SECTION 16 - ADDITIONAL INFORMATION
N/A

推荐供应商更多供应商>>

湖北万知化工医药股份有限公司

产品介绍:
产品名称:卡波姆940 Cas号:9007-20-9 纯度:99% 包装信息:1g 价格:100.0元
联系方式:
联系人:王 电话:02784492310 手机:13657243668

湖北诺纳科技有限公司

产品介绍:
产品名称:聚丙烯酸 Cas号:9007-20-9 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶 价格:1.0元 - 25.0元
联系方式:
联系人:张经理 电话:027-59209883 手机:17386169806

湖北云镁科技有限公司

产品介绍:
产品名称:聚丙烯酸 Cas号:9007-20-9 纯度:99% 包装信息:227kg,1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶,1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶 价格:1.0元 - 227.0元
联系方式:
联系人:方经理 电话:027-59206672 手机:18327059871

湖北齐飞医药化工有限公司

产品介绍:
产品名称:聚丙烯酸 Cas号:9007-20-9 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:朱梦蝶 电话:027-59322506 手机:18071128683

湖北实顺生物科技有限公司

产品介绍:
产品名称:聚丙烯酸 Cas号:9007-20-9 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:张经理 电话:027-59223025 手机:15172526927

湖北永阔科技有限公司

产品介绍:
产品名称:聚丙烯酸 Cas号:9007-20-9 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:徐 电话:027-59223108 手机:15107166787

天门恒昌化工有限公司

产品介绍:
产品名称:聚丙烯酸 Cas号:9007-20-9 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:黄经理 电话:027-59322316 手机:15827039378

湖北常鑫盛化工有限公司

产品介绍:
产品名称:卡波姆 Cas号:9007-20-9 纯度:98% 包装信息:1kg,25kg,100kg,1000kg 价格:1.0元 - 10.0元
联系方式:
联系人:黄 电话:18971203904 手机:18971203904

特斯科化工(湖北)有限公司

产品介绍:
产品名称:卡波姆 Cas号:9007-20-9 纯度:99% 包装信息:1000kg箱,25kg桶,1kg袋 价格:洽谈
联系方式:
联系人:郑先生 电话:18971353902 手机:18971353902

武汉卡诺斯科技有限公司

产品介绍:
产品名称:卡波姆 940 Cas号:9007-20-9 纯度:30% 包装信息:25千克 价格:42.0元
联系方式:
联系人:尚文 电话:153-37111468 手机:15337111468