5,6-联苯基-3-(2-吡啶基)-1,2,4-三吖嗪

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品
  • 表征图谱

5,6-联苯基-3-(2-吡啶基)-1,2,4-三吖嗪 基本信息

中文名称:
5,6-联苯基-3-(2-吡啶基)-1,2,4-三吖嗪 
中文别名:
3-(2-吡啶基)-5,6-二苯基-1,2,4-三嗪;
5,6-联苯基-3-(2-吡啶基)-1,2,4-三吖嗪 
英文名称:
1,2,4-Triazine,5,6-diphenyl-3-(2-pyridinyl)-
英文别名:
3-(2-PYRIDYL)-5,6-DIPHENYL-1,2,4-TRIAZINE;
5,6-diphenyl-3-pyridin-2-yl-1,2,4-triazine;
5,6-Diphenyl-3-(2-pyridyl)-1,2,4-triazine 
CAS No.:
1046-56-6
分 子 式:
C20H14N4
分 子 量:
310.35
精确分子量:
310.12200
PSA:
51.56000
MDL:
MFCD00006462
EINECS:
213-878-7
BRN:
542151
InChI:
InChI=1/C20H14N4/c1-3-9-15(10-4-1)18-19(16-11-5-2-6-12-16)23-24-20(22-18)17-13-7-8-14-21-17/h1-14H
危险品标志:
IrritantXi
风险术语:
R36/37/38
安全术语:
S24/25
分子结构式:
SDS:
查看

5,6-联苯基-3-(2-吡啶基)-1,2,4-三吖嗪 物化性质

外观与性状:
黄色粉末
密度:
1.202g/cm3
熔点:
191-193 °C(lit.)
沸点:
525.3ºC at 760mmHg
闪点:
237.7ºC
折射率:
1.634
蒸汽压:
1.33E-10mmHg at 25°C
存储条件/存储方法:

保持容器密封,储存在阴凉,干燥的地方 

稳定性相关:

常温常压下稳定,避免氧化物接触

其它信息:

1.      性状:未确定。

2.      密度(g/cm3,25):未确定

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):191-193

5.      沸点(ºC,常压):未确定

6.      沸点(ºC,8mm):未确定

7.      折射率:未确定

8.      闪点(ºC):未确定

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,25ºC):未确定

12.   饱和蒸气压(kPa,60ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:未确定

5,6-联苯基-3-(2-吡啶基)-1,2,4-三吖嗪 安全信息

海关代码:
2933990090
WGK_Germany:
3
德国有关水污染物质的分类清单
危险类别码:
R36/37/38
安全说明:
S26-S36
RTECS号:
XY8598150
危险标志:
Xi: Irritant;

5,6-联苯基-3-(2-吡啶基)-1,2,4-三吖嗪 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XY8598150
CHEMICAL NAME :
1,2,4-Triazine, 5,6-diphenyl-3-(2-pyridinyl)-
CAS REGISTRY NUMBER :
1046-56-6
BEILSTEIN REFERENCE NO. :
0542151
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C20-H14-N4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - quail
DOSE/DURATION :
>316 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
EESADV Ecotoxicology and Environmental Safety. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1977- Volume(issue)/page/year: 6,149,1982
毒理学数据:

1、急性毒性:鹌鹑口经LD50>316mg/kg

生态数据:

对水是稍微有害的,不要让未稀释或大量的产品接触地下水,水道或者污水系统,若无政府许可,勿将材料排入周围环境储存

5,6-联苯基-3-(2-吡啶基)-1,2,4-三吖嗪 MSDS

Name: 3-(2-Pyridyl)-5 6-Diphenyl-1 2 4-Triazine 99+% Material Safety Data Sheet
Synonym: 5,6-Diphenyl-3-(2-Pyridyl)-1,2,4-Triazine; PDT
CAS: 1046-56-6
Section 1 - Chemical Product   MSDS Name:3-(2-Pyridyl)-5 6-Diphenyl-1 2 4-Triazine 99+% Material Safety Data Sheet
Synonym:5,6-Diphenyl-3-(2-Pyridyl)-1,2,4-Triazine; PDT

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
1046-56-6 3-(2-Pyridyl)-5,6-Diphenyl-1,2,4-Triaz 99+% 213-878-7
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1046-56-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Powder
Color: yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 191.00 - 193.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: slightly soluble
Specific Gravity/Density:
Molecular Formula: C20H14N4
Molecular Weight: 310.35

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 1046-56-6: XY8598150 LD50/LC50:
Not available.
Carcinogenicity:
3-(2-Pyridyl)-5,6-Diphenyl-1,2,4-Triazine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1046-56-6: No information available.
Canada
CAS# 1046-56-6 is listed on Canada's DSL List.
CAS# 1046-56-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1046-56-6 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

5,6-联苯基-3-(2-吡啶基)-1,2,4-三吖嗪 海关数据

中国海关编码:2933990090

概述:
2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途, 乌洛托品请注明外观, 6-己内酰胺请注明外观, 签约日期
摘要/Summary:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

5,6-联苯基-3-(2-吡啶基)-1,2,4-三吖嗪 分子结构与计算化学数据

分子结构数据

1、   摩尔折射率:92.39

2、   摩尔体积m3/mol258.1                

3、   等张比容90.2K703.9

4、   表面张力dyne/cm55.2

5、   介电常数:无可用

6、   偶极距10-24cm3:无可用

7、   极化率:36.62

计算化学数据

1.疏水参数计算参考值(XlogP):3.1

2.氢键供体数量:0

3.氢键受体数量:4

4.可旋转化学键数量:3

5.互变异构体数量:无

6.拓扑分子极性表面积51.6

7.重原子数量:24

8.表面电荷:0

9.复杂度:376

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

5,6-联苯基-3-(2-吡啶基)-1,2,4-三吖嗪 下游产品

5,6-联苯基-3-(2-吡啶基)-1,2,4-三吖嗪 表征图谱

推荐供应商更多供应商>>

北京百灵威科技有限公司

产品介绍:
产品名称:3-(2-吡啶基)-5,6-二苯基-1,2,4-三嗪 532325 Cas号:1046-56-6 纯度:99% 包装信息:1g,5g 价格:洽谈
联系方式:
联系人:翟先生 电话:18210857532 手机:18210857532

山东默派生物科技有限公司

产品介绍:
产品名称:3-(2-吡啶基)-5,6-二苯基-1,2,4-三嗪 Cas号:1046-56-6 纯度:99% 包装信息:1kg 价格:洽谈
联系方式:
联系人:张经理 电话:13070690626 手机:13070690626

湖北恩星生物科技有限公司

产品介绍:
产品名称:3-(2-吡啶基)-5,6-二苯基-1,2,4-三嗪 Cas号:1046-56-6 纯度: 包装信息:100kg,200kg,300kg,400kg,500kg 价格:64.0元 - 100.0元
联系方式:
联系人:邵经理 电话:16621771607 手机:16621771607

上海瀚思化工有限公司

产品介绍:
产品名称:5,6-二苯基-3-(2-吡啶基)-1,2,4-三嗪 Cas号:1046-56-6 纯度:98% 包装信息:25g 价格:2,539.0元
联系方式:
联系人:张 电话:021-64806089 手机:18049821080

西格玛奥德里奇

产品介绍:
产品名称:3-(2-吡啶基)-5,6-二苯基-1,2,4-三嗪 Cas号:1046-56-6 纯度:>=99% 包装信息:g-kg 价格:洽谈
联系方式:
联系人:默克 电话:021-61514946 手机:

郑州杰克斯化工有限公司

产品介绍:
产品名称:5,6-联苯基-3-(2-吡啶基)-1,2,4-三吖嗪 Cas号:1046-56-6 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:许伟伟 电话:0371-86259281 15981966935 手机:15981966935

阿法埃莎(天津)化学有限公司

产品介绍:
产品名称:5,6-联苯基-3-(2-吡啶基)-1,2,4-三吖嗪 Cas号:1046-56-6 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:张海滨 电话:800-810-6000 手机:

北京海步国际医药科技发展有限公司

产品介绍:
产品名称:3-(2-吡啶基)-5,6-二苯基-1,2,4-三嗪 Cas号:1046-56-6 纯度:98%-99% 包装信息:2kg 价格:洽谈
联系方式:
联系人: 电话:86-10-67886402 手机: