四氨基铂合四氯化铂

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学
  • 上游产品
  • 下游产品
  • 表征图谱

四氨基铂合四氯化铂 基本信息

中文名称:
四氨基铂合四氯化铂 
中文别名:
四氨基铂(II)合四氯化铂(II);
四氨基铂合四氯化铂 
英文名称:
Tetraammineplatinum (II) tetrachloroplatinate (II)
英文别名:
TETRAAMMINEPLATINUM(II) TETRACHLORO-;
Platinum(2+),tetraammine-,(sp-4-1)-,(sp-4-1)-tetrachloroplatinate(2-) (1:1);
{Pta4}{PtCl4} [Pt(NH3)4][PtCl4],green;
Magnus green salt;
Tetrammin-platin(II)-tetrachloro-platinat(II);
tetraammine-platinum(II) tetrachloro-platinate(II);
Tetraammineplatinous tetrachloroplatinate;
tetraammineplatinum tetrachloroplatinate;
Tetrammineplatinum(ii) tetrachloroplatinate(ii);
{Pta4}{PtCl4};
tetraammine-platinum(2++(sp-4-1)-platinum(2++(sp-4-1)-tetrachloroplatinate(2-)(1:1) 
CAS No.:
13820-46-7
分 子 式:
H12Cl4N4Pt2
分 子 量:
600.09
精确分子量:
597.91100
PSA:
12.96000
MDL:
MFCD01459899
EINECS:
237-501-0
InChI:
The Key: UBTDQVRNDDEBSJ-UHFFFAOYSA-J
风险术语:
R25;R41;R42/43
安全术语:
S22;S26;S45;36/37/39
分子结构式:
SDS:
查看

四氨基铂合四氯化铂 物化性质

熔点:
320ºC (dec.)(lit.)
存储条件/存储方法:

常温密闭,阴凉通风干燥

稳定性相关:

常温常压下稳定

避免的物料  氧化物

其它信息:

1.      性状:绿色粉末

2.      密度(g/mL,25/4):4

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):320

5.      沸点(ºC,常压):未确定

6.      沸点(ºC,5.2kPa):未确定

7.      折射率:未确定

8.      闪点(ºC):未确定

9.      比旋光度º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,25ºC):未确定

12.   饱和蒸气压(kPa,60ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:不能溶解的

四氨基铂合四氯化铂 安全信息

危险类别码:
R25
安全说明:
22-26-36/37/39-45
安全标志:
S22:不要吸入粉尘。
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
:
危险标志:
T: Toxic;

四氨基铂合四氯化铂 毒理性

毒理学数据:

1、急性毒性:主要的刺激性影响:

在皮肤上面:刺激皮肤和粘膜;

在眼睛上面:刺激的影响;

2、致敏作用:通过吸入可能造成敏化作用,通过皮肤接触可能造成敏化作用。

生态数据:

通常对水体是稍微有害的,不要将未稀释或大量产品接触地下水,水道或污水系统,未经政府许可勿将材料排入周围环境。

四氨基铂合四氯化铂 MSDS


Section 1: Product Identification
   Chemical Name:       Tetraammineplatinum (II) tetrachloroplatinate (II), 99%    
   CAS Registry Number:       13820-46-7    
   Formula:       [Pt(NH3)4][PtCl4]    
   EINECS Number:       237-501-0    
   Chemical Family:       metal-ammine complexes    
   Synonym:       Platinum (II) tetraammine tetrachloroplatinate (II)    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       13820-46-7       100%       1mg/m3(as-Pt)       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract. May cause sensitization by skin contact.    
   Primary Routes of Exposure:       Ingestion, inhalation, skin    
   Eye Contact:       Causes mild to moderate irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin. May cause sensitization by skin contact.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.    
   Irritating to skin, eyes and respiratory tract. Exposure to platinum compounds may lead to wheezing, coughing,
   Acute Health Affects:
   and running of the nose. Skin exposure may lead to dermatitis.
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic and corrosive fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a cool, dry place in a tightly sealed container.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       To minimize exposure, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       To minimize exposure, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       green pwdr.    
   Molecular Weight:       600.12    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       active metals    
   Decomposition Products:       ammonium chloride, nitrogen oxides, and platinum salts.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data    
   Mutagenic Effects:       No data    
   Tetratogenic Effects:       No data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Not regulated by Title 313.    
   Second Ingredient:       None    


SECTION 16 - ADDITIONAL INFORMATION
N/A

四氨基铂合四氯化铂 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:597.911207Da

8、标称质量:598Da

9、平均质量:600.1021Da

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:4

3.氢键受体数量:8

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积4

7.重原子数量:10

8.表面电荷:0

9.复杂度:0

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:10

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