4-(3-硝基-2-吡啶基)吗啉

  • 基本信息
  • 物化性质
  • 安全信息
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品

4-(3-硝基-2-吡啶基)吗啉 基本信息

中文名称:
4-(3-硝基-2-吡啶基)吗啉 
中文别名:
4-(3-硝基-2-吡啶基)吗啉;
N-(3-硝基-2-吡啶基)吗啉 
英文名称:
Morpholine,4-(3-nitro-2-pyridinyl)-
英文别名:
4-(3-nitropyridin-2-yl)morpholine;
4-(3-Nitro-pyridin-2-yl)-morpholine;
N-(3-Nitro-2-pyridyl)morpholine;
4-{3-nitro-2-pyridinyl}morpholine;
4-(3-nitropyridine-2-yl)morpholine;
nitropyridinylmorpholine;
4-(3-nitro-2-pyridyl)morpholine 
CAS No.:
24255-27-4
分 子 式:
C9H11N3O3
分 子 量:
209.2019
精确分子量:
209.08000
PSA:
71.18000
InChI:
The Key: QMINJWUSSJFQBR-UHFFFAOYSA-N
分子结构式:
SDS:
查看

4-(3-硝基-2-吡啶基)吗啉 物化性质

密度:
1.325g/cm3
熔点:
91-94ºC
沸点:
375.8ºC at 760mmHg
闪点:
181.1ºC
蒸汽压:
7.56E-06mmHg at 25°C
其它信息:

1. 熔点(ºC):91~94

4-(3-硝基-2-吡啶基)吗啉 安全信息

海关代码:
2934999090

4-(3-硝基-2-吡啶基)吗啉 MSDS

Name: 4-(3-Nitro-2-pyridinyl)morpholine Material Safety Data Sheet
Synonym:
CAS: 24255-27-4
Section 1 - Chemical Product   MSDS Name:4-(3-Nitro-2-pyridinyl)morpholine Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
24255-27-4 4-(3-Nitro-2-pyridinyl)morpholine 97+% unlisted
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 24255-27-4: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: Orange
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 89 - 90 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C9H11N3O3
Molecular Weight: 209.21

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Not available.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 24255-27-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-(3-Nitro-2-pyridinyl)morpholine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 24255-27-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 24255-27-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 24255-27-4 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

4-(3-硝基-2-吡啶基)吗啉 海关数据

中国海关编码:2934999090

概述:
2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

4-(3-硝基-2-吡啶基)吗啉 分子结构与计算化学数据

分子结构数据

1、  摩尔折射率:52.69

2、  摩尔体积(cm3/mol):157.8

3、  等张比容(90.2K):433.6

4、  表面张力(dyne/cm):57.0

5、  极化率(10-24cm3):20.89

计算化学数据

1.疏水参数计算参考值(XlogP):0.8

2.氢键供体数量:0

3.氢键受体数量:5

4.可旋转化学键数量:1

5.互变异构体数量:无

6.拓扑分子极性表面积71.2

7.重原子数量:15

8.表面电荷:0

9.复杂度:225

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

4-(3-硝基-2-吡啶基)吗啉 上游产品

4-(3-硝基-2-吡啶基)吗啉 下游产品

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