4-甲氧基二苯乙烯

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学
  • 上游产品
  • 下游产品

4-甲氧基二苯乙烯 基本信息

中文名称:
4-甲氧基二苯乙烯 
中文别名:
4-甲氧基芪;
4-甲氧基二苯乙烯 
英文名称:
Benzene,1-methoxy-4-(2-phenylethenyl)-
英文别名:
4-METHOXYSTILBENE;
4-methoxy-trans-stilbene radical-cation;
4-Methoxy-cis-stilbene;
Anisole,p-styryl;
trans-4-methoxystilbene radical cation;
1-Styryl-4-methoxybenzene;
4-Methoxy-trans-stilbene;
Anisole,p-styryl-(6CI,7CI,8CI);
4-Methoxystilbene;
Methoxystilbene,4;
p-Methoxystilbene 
CAS No.:
1142-15-0
分 子 式:
C15H14O
分 子 量:
210.28
精确分子量:
210.10400
PSA:
9.23000
MDL:
MFCD00017178
EINECS:
214-530-7
InChI:
The Key: XWYXLYCDZKRCAD-BQYQJAHWSA-N
风险术语:
R36
安全术语:
S24/25
分子结构式:
SDS:
查看

4-甲氧基二苯乙烯 物化性质

密度:
1.069g/cm3
熔点:
135-138 °C
沸点:
341.5ºC at 760 mmHg
闪点:
135.4ºC
折射率:
1.634
蒸汽压:
0.000159mmHg at 25°C
存储条件/存储方法:

保持贮藏器密封、储存在阴凉、干燥的地方,确保工作间有良好的通风或排气装置

稳定性相关:

如果遵照规格使用和储存则不会分解,未有已知危险反应,避免氧化物

其它信息:

1.      性状:粉末

2.      密度(g/mL,25):未确定3.      相对蒸汽密度(g/mL,空气=1):未确定4.      熔点(ºC):135-1385.      沸点(ºC,常压):未确定6.      沸点(ºC,4mmHg):未确定7.      折射率(n20/D未确定8.      闪点(ºC,0.6mm):未确定9.      比旋光度(º):未确定10.   自燃点或引燃温度(ºC):未确定11.   蒸气压(mmHg,20ºC):未确定12.   饱和蒸气压(kPa,60ºC):未确定13.   燃烧热(KJ/mol):未确定14.   临界温度(ºC):未确定15.   临界压力(KPa):未确定16.   油水(辛醇/水)分配系数的对数值:未确定17.   爆炸上限(%,V/V):未确定18.   爆炸下限(%,V/V):未确定19.   溶解性:未确定

4-甲氧基二苯乙烯 安全信息

危险类别码:
R36
安全说明:
S39-S26
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S39:佩戴眼/面防护装置。
危险标志:
Xi

4-甲氧基二苯乙烯 毒理性

生态数据:

对水是稍微有危害的不要让未稀释或大量的产品接触地下水、水道或者污水系统,若无政府许可,勿将材料排入周围环境。

4-甲氧基二苯乙烯 MSDS

Name: 4-Methoxystilbene 98+% Material Safety Data Sheet
Synonym: None Known
CAS: 1142-15-0
Section 1 - Chemical Product   MSDS Name:4-Methoxystilbene 98+% Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
1142-15-0 4-Methoxystilbene 98+ 214-530-7
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use agent most appropriate to extinguish fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 1142-15-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Powder
Color: light yellow to green
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 136.00 - 138.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C15H14O
Molecular Weight: 210.27

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 1142-15-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Methoxystilbene - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 1142-15-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1142-15-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1142-15-0 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

4-甲氧基二苯乙烯 分子结构与计算化学数据

分子结构数据

1、  摩尔折射率:70.32

2、  摩尔体积(m3/mol):196.6

3、  等张比容(90.2K):498.6

4、  表面张力(dyne/cm):41.3

5、  极化率10-24cm3):27.87

  

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:1

4.可旋转化学键数量:3

5.互变异构体数量:无

6.拓扑分子极性表面积9.2

7.重原子数量:16

8.表面电荷:0

9.复杂度:208

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:1

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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