乙酰胺甘醇酸

  • 基本信息
  • 物化性质
  • 安全信息
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品

乙酰胺甘醇酸 基本信息

中文名称:
乙酰胺甘醇酸 
中文别名:
2-羟基-2-[(1-氧代-2-丙烯基)氨基]乙酸 
英文名称:
Acetic acid,2-hydroxy-2-[(1-oxo-2-propen-1-yl)amino]-
英文别名:
2-hydroxy-2-(prop-2-enoylamino)acetic acid;
HF 7630;
2-Acrylamidoglycolic acid;
Acrylamido-N-glykolsaeure;
EINECS 229-790-7;
acrylamido-glycolic acid;
2-acrylamido-2-hydroxy-acetic acid 
CAS No.:
6737-24-2
分 子 式:
C5H7NO4
分 子 量:
145.11
精确分子量:
145.03800
PSA:
90.12000
EINECS:
229-790-7
InChI:
The Key: NEYTXADIGVEHQD-UHFFFAOYSA-N
风险术语:
R10R22R34R41R67R36/37/38
安全术语:
S16S22S24S26S36S39S24/25<a href="http://www.lookchem.cn/safet#S36/S37/
分子结构式:
SDS:
查看

乙酰胺甘醇酸 物化性质

密度:
0.82 g/mL at 20ºC
熔点:
123-127ºC
沸点:
465.3ºC at 760 mmHg
闪点:
22ºC
折射率:
n20/D 1.479
其它信息:

1.     性状:未确定

2.     密度(g/mL,25):0.823.     相对蒸汽密度(g/mL,空气=1):未确定4.     熔点(ºC):123-1275.     沸点(ºC,常压):未确定6.     沸点(ºC,15mmHg):未确定7.     折射率(n20/D):1.4798.     闪点(ºC):229.     比旋光度(º):未确定10.  自燃点或引燃温度(ºC):未确定11.  蒸气压(mmHg,217ºC):未确定12.  饱和蒸气压(kPa,25ºC):未确定13.  燃烧热(KJ/mol):未确定14.  临界温度(ºC):未确定15.  临界压力(KPa):未确定16.  油水(辛醇/水)分配系数的对数值:未确定17.  爆炸上限(%,V/V):未确定18.  爆炸下限(%,V/V):未确定19.  溶解性:溶于水

乙酰胺甘醇酸 安全信息

包装等级:
III
海关代码:
2924199090
危险类别码:
36/37/38-67-41-10-22-34
安全说明:
26-36-39-24-16-24/25-22-45-36/37/39
安全标志:
S16:远离火源。
S22:不要吸入粉尘。
S24:避免接触皮肤。
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S36:穿戴合适的防护服装。
S39:佩戴眼/面防护装置。
S24/25:防止皮肤和眼睛接触。
:
危险标志:
Xi,Xn,C

乙酰胺甘醇酸 MSDS

Name: Acrylamido Glycolic Acid Anhydrous 98% Material Safety Data Sheet
Synonym: 2-Hydroxy-2-[(1-Oxo-2-Propenyl)amino]acetic Aci
CAS: 6737-24-2
Section 1 - Chemical Product   MSDS Name:Acrylamido Glycolic Acid Anhydrous 98% Material Safety Data Sheet
Synonym:2-Hydroxy-2-[(1-Oxo-2-Propenyl)amino]acetic Aci

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
6737-24-2 Acrylamido Glycolic Acid 98 229-790-7
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Causes burns.Light sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.
Inhalation:
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Store protected from light. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Store protected from light.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 6737-24-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: Not available.
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 125 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C5H7NO4
Molecular Weight: 145.11

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, dust generation, excess heat, oxidizers.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 6737-24-2: AI2510000 LD50/LC50:
Not available.
Carcinogenicity:
Acrylamido Glycolic Acid - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 6737-24-2: No information available.
Canada
CAS# 6737-24-2 is listed on Canada's NDSL List.
CAS# 6737-24-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6737-24-2 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

乙酰胺甘醇酸 海关数据

中国海关编码:2924199090

概述:
2924199090. 其他无环酰胺(包括无环氨基甲酸酯)(包括其衍生物及盐). 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素:
品名, 成分含量, 用途, 包装
摘要/Summary:
2924199090. other acyclic amides (including acyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

乙酰胺甘醇酸 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):-0.8

2.氢键供体数量:3

3.氢键受体数量:4

4.可旋转化学键数量:3

5.互变异构体数量:2

6.拓扑分子极性表面积86.6

7.重原子数量:10

8.表面电荷:0

9.复杂度:165

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:1

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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