过氯酰氟

密度：

1.434

熔点：

-146ºC

沸点：

-46.8ºC

存储条件/存储方法：

库房通风低温干燥,与酸、碱、易燃物、还原剂分开存放

风险类别：

2.2

CHEMICAL IDENTIFICATION

RTECS NUMBER :

SD1925000

CHEMICAL NAME :

Perchloryl fluoride

CAS REGISTRY NUMBER :

7616-94-6

LAST UPDATED :

199712

DATA ITEMS CITED :

24

MOLECULAR FORMULA :

Cl-F-O3

MOLECULAR WEIGHT :

102.45

WISWESSER LINE NOTATION :

O3 F G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :

Inhalation

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

385 ppm/4H

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

PENNS* Pennsalt Chemicals Corp., Technical Div., New Products. (Philadelphia, PA)

TYPE OF TEST :

LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :

Inhalation

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

630 ppm/4H

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

PENNS* Pennsalt Chemicals Corp., Technical Div., New Products. (Philadelphia, PA)

TYPE OF TEST :

LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :

Inhalation

SPECIES OBSERVED :

Mammal - dog

DOSE/DURATION :

451 ppm/4H

REFERENCE :

XAWPA2 U.S. Army Chemical Warfare Laboratories. (Army Chemical Center, MD) Volume(issue)/page/year: CWL 2-10,1958 *** REVIEWS *** ACGIH TLV-STEL 25 mg/m3 (6 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 13 mg/m3 (3 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 3 ppm (14 mg/m3) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,202,1971 OSHA PEL (Gen Indu):8H TWA 3 ppm (13.5 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 3 ppm (13.5 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 3 ppm (13.5 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 3 ppm (13.5 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 3 ppm (14 mg/m3);STEL 6 ppm (28 mg/m3) JAN 1993 OEL-BELGIUM:TWA 3 ppm (13 mg/m3);STEL 6 ppm (25 mg/m3) JAN 1993 OEL-DENMARK:TWA 2 mg/m3 JAN 1993 OEL-DENMARK:TWA 3 ppm (14 mg/m3) JAN 1993 OEL-FINLAND:TWA 3 ppm (14 mg/m3);STEL 6 ppm (25 mg/m3) JAN 1993 OEL-FRANCE:TWA 3 ppm (14 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 3 ppm (14 mg/m3) JAN 1993 OEL-THE PHILIPPINES:TWA 3 ppm (10.5 mg/m3) JAN 1993 OEL-SWITZERLAND:TWA 3 ppm (13 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 3 ppm (14 mg/m3);STEL 6 ppm (28 mg/m3) JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO PERCHLORYL FLUORIDE-air:10H TWA 3 ppm;STEL 6 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992