(-)-1,1-双((2S,4S)-2,4-二乙基膦)二茂铁

  • 基本信息
  • 物化性质
  • 安全信息
  • MSDS

(-)-1,1-双((2S,4S)-2,4-二乙基膦)二茂铁 基本信息

中文名称:
(-)-1,1-双((2S,4S)-2,4-二乙基膦)二茂铁 
中文别名:
(-)-1,1-双((2S,4S)-2,4-二乙基膦)二茂铁;
(-)-1,1'-双((2S,4S)-2,4-二乙基膦)二茂铁;
(-)-1,1'-双((2S,4S)-2,4-二乙基膦)双环戊二烯 
英文名称:
Ferrocene,1,1'-bis[(2S,4S)-2,4-diethyl-1-phosphetanyl]-, stereoisomer
英文别名:
(-)-1,1'-BIS((2S,4S)-2,4-DIETHYLPHOSPHOTANO)FERROCENE;
Et-Ferrotane;
Carbonotrithioic acid,dimethyl ester;
R,R-Et-FerroTANE;
Dimethyl trithiocarbonate;
CARBONIC ACID,TRITHIO-,DIMETHYL ESTER;
S,S-dimethyl trithiocarbonate;
Trithiocarbonic acid dimethyl ester;
dimethyl carbonotrithioate 
CAS No.:
290347-66-9
分 子 式:
C24H36FeP2
分 子 量:
442.34
精确分子量:
442.16400
PSA:
27.18000
InChI:
The Key: LVYUAEWNPLZXSA-UYRFGRJHSA-N
风险术语:
R36/37/38
安全术语:
S26S36/S37/S39
分子结构式:
SDS:
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(-)-1,1-双((2S,4S)-2,4-二乙基膦)二茂铁 物化性质

熔点:
76ºC
其它信息:

1.      性状:未确定

2.      密度(g/mL):未确定

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):76

5.      沸点(ºC,常压):未确定

6.      沸点(ºC0.8mmHg):未确定

7.      折射率:未确定

8.      闪点(ºF):未确定

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,):未确定

12.   饱和蒸气压(kPa,60ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:未确定

(-)-1,1-双((2S,4S)-2,4-二乙基膦)二茂铁 安全信息

危险类别码:
36/37/38
安全说明:
26-36/37/39
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:

(-)-1,1-双((2S,4S)-2,4-二乙基膦)二茂铁 MSDS


Section 1: Product Identification
   Chemical Name:       (-)-1,1'-Bis((2S,4S)-2,4-diethylphosphotano)ferrocene, min. 95% (S,S)-Et-FerroTANE®    
   CAS Registry Number:       290347-66-9    
   Formula:       [C5H4(C7H14P)]2Fe    
   EINECS Number:       none    
   Chemical Family:       organometallic complexes    
   Synonym:       none    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       290347-66-9       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and mucous membranes.    
   Primary Routes of Exposure:       Ingestion, skin, inhalation, eyes    
   Eye Contact:       Causes slight to mild irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No information available on the physiological effects of ingestion.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit irritating fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a cool, dry area away from heat and direct sunlight.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       yellow-orange pwdr.    
   Molecular Weight:       442.35    
   Melting Point:       76°    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       no data    
   Solubility in Water:       no data    

SECTION 10: Stability and Reactivity
   Stability:       air-sensitive solid    
   Hazardous Polymerization:       none    
   Conditions to Avoid:       none    
   Incompatibility:       strong oxidizing agents    
   Decomposition Products:       carbon dioxide, carbon monoxide, organic fumes, phosphorus oxides, and iron oxide.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Not reportable under SARA Title 313    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

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产品介绍:
产品名称:(-)-1,1-双((2S,4S)-2,4-二乙基膦)二茂铁 Cas号:290347-66-9 纯度: 包装信息:洽谈 价格:洽谈
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产品介绍:
产品名称:(-)-1,1-双((2S,4S)-2,4-二乙基膦)二茂铁 Cas号:290347-66-9 纯度: 包装信息:洽谈 价格:洽谈
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