3-羟基-2-甲基-4-喹啉甲酸

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品

3-羟基-2-甲基-4-喹啉甲酸 基本信息

中文名称:
3-羟基-2-甲基-4-喹啉甲酸 
中文别名:
2-甲基-3-羟基喹啉-4-羧酸;
3-羟基-2-甲基-4-喹啉羧酸;
3-羟基喹哪啶-4-甲酸;
2-甲基-3-羟基喹啉-4-甲酸 
英文名称:
4-Quinolinecarboxylicacid, 3-hydroxy-2-methyl-
英文别名:
3-Hydroxy-2-methylquinoline-4-carboxylic acid;
3-Hydroxy-2-methyl-4-quinolinecarboxylic acid;
3-hydroxy-2-methylquinoline-4-carboxylic acid 
CAS No.:
117-57-7
分 子 式:
C11H9NO3
分 子 量:
203.19
精确分子量:
203.05800
PSA:
70.42000
MDL:
MFCD00044850
EINECS:
204-198-1
InChI:
The Key: RVGATDHHYVSTQG-UHFFFAOYSA-N
危险品标志:
Xn
风险术语:
R22R36/37/38
安全术语:
S22S26S36/S37/S39S37/S39
分子结构式:
SDS:
查看

3-羟基-2-甲基-4-喹啉甲酸 制备方法及用途

制备方法

合成染料分散黄54#的重要中间体

用途简介

用途

合成染料分散黄54#的重要中间体

3-羟基-2-甲基-4-喹啉甲酸 物化性质

外观与性状:
黄色至绿色粉末
密度:
1.41 g/cm3
熔点:
235 °C (dec.)(lit.)
沸点:
370.2ºC at 760 mmHg
闪点:
252 °C
水溶解性:
0.04 g/L (20 ºC)
蒸汽压:
3.91E-06mmHg at 25°C
存储条件/存储方法:

密封储存,储存于阴凉、干燥的库房。

稳定性相关:

常温常压下稳定,避免与不相容材料,强氧化剂接触。

3-羟基-2-甲基-4-喹啉甲酸 安全信息

海关代码:
2933499090
WGK_Germany:
1
德国有关水污染物质的分类清单
危险类别码:
R22;R36/37/38
安全说明:
S26-S37/39-S36/37/39-S22
安全标志:
S22:不要吸入粉尘。
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:
:
危险标志:
Xn: Harmful;

3-羟基-2-甲基-4-喹啉甲酸 MSDS

Name: 3-Hydroxy-2-Methyl-4-Quinolinecarboxylic Acid 99% Material Safety Data Sheet
Synonym: None known
CAS: 117-57-7
Section 1 - Chemical Product   MSDS Name:3-Hydroxy-2-Methyl-4-Quinolinecarboxylic Acid 99% Material Safety Data Sheet
Synonym:None known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
117-57-7 3-Hydroxy-2-Methyl-4-Quinolinecarboxyl 99 204-198-1
Hazard Symbols: XN
Risk Phrases: 22

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful if swallowed.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 117-57-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Powder
Color: yellow to green
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 220.00 - 223.00 deg C
Autoignition Temperature: 440 deg C ( 824.00 deg F)
Flash Point: 252 deg C ( 485.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >190 deg C
Solubility in water: 0.04 g/l (20 c)
Specific Gravity/Density:
Molecular Formula: C11H9NO3
Molecular Weight: 203.20

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 117-57-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3-Hydroxy-2-Methyl-4-Quinolinecarboxylic Acid - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 117-57-7: 1
Canada
CAS# 117-57-7 is listed on Canada's NDSL List.
CAS# 117-57-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 117-57-7 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

3-羟基-2-甲基-4-喹啉甲酸 海关数据

中国海关编码:2933499090

概述:
2933499090. 其他含喹琳或异喹啉环系的化合物〔但未进一步稠合的〕. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途, 乌洛托品请注明外观, 6-己内酰胺请注明外观, 签约日期
摘要/Summary:
2933499090. other compounds containing in the structure a quinoline or isoquinoline ring-system (whether or not hydrogenated), not further fused. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

3-羟基-2-甲基-4-喹啉甲酸 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:55.82

2、摩尔体积(cm3/mol):144

3、等张比容(90.2K):420

4、表面张力(dyne/cm):72.3

5、介电常数:无可用的

6、极化率(10-24cm3):22.13

7、单一同位素质量:203.058243 Da

8、标称质量:203 Da

9、平均质量:203.1941 Da

计算化学数据

1.疏水参数计算参考值(XlogP):2.3

2.氢键供体数量:2

3.氢键受体数量:4

4.可旋转化学键数量:1

5.互变异构体数量:7

6.拓扑分子极性表面积70.4

7.重原子数量:15

8.表面电荷:0

9.复杂度:256

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

推荐供应商更多供应商>>

湖北云镁科技有限公司

产品介绍:
产品名称:2-甲基-3-羟基喹啉-4-羧酸 Cas号:117-57-7 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶 价格:1.0元 - 25.0元
联系方式:
联系人:方经理 电话:027-59206672 手机:18327059871

湖北诺纳科技有限公司

产品介绍:
产品名称:2-甲基-3-羟基喹啉-4-羧酸 Cas号:117-57-7 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶 价格:1.0元 - 25.0元
联系方式:
联系人:张经理 电话:027-59209883 手机:17386169806

湖北万得化工有限公司

产品介绍:
产品名称:3-羟基-2-甲基-4-喹啉甲酸 Cas号:117-57-7 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶,200kg镀锌铁桶/塑料桶,1t吨袋 价格:1.0元 - 1,000.0元
联系方式:
联系人:王念 电话:027-59210159 手机:15172311821

湖北巨胜科技有限公司

产品介绍:
产品名称:3-羟基-2-甲基-4-喹啉甲酸 Cas号:117-57-7 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:孙敏 电话:027-59599240 手机:18702754003

湖北齐飞医药化工有限公司

产品介绍:
产品名称:2-甲基-3-羟基喹啉-4-羧酸 Cas号:117-57-7 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:汪军蕊(微信同号) 电话:027-59322506 手机:18071128683

天门恒昌化工有限公司

产品介绍:
产品名称:2-甲基-3-羟基喹啉-4-羧酸 Cas号:117-57-7 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:黄湘迪 电话:027-59322316 手机:15827039378

湖北永阔科技有限公司

产品介绍:
产品名称:2-甲基-3-羟基喹啉-4-羧酸 Cas号:117-57-7 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:黄蓉 电话:027-59223108 手机:15107166787

湖北实顺生物科技有限公司

产品介绍:
产品名称:2-甲基-3-羟基喹啉-4-羧酸 Cas号:117-57-7 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:付经理 电话:027-59223025 手机:15107168801

湖北广奥生物科技有限公司

产品介绍:
产品名称:3-羟基-2-甲基-4-喹啉甲酸 Cas号:117-57-7 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶,200kg镀锌铁桶/塑料桶,1t吨袋 价格:1.0元 - 1,000.0元
联系方式:
联系人:付玉 电话:027-59223056 手机:15271829679

湖北信康医药化工有限公司

产品介绍:
产品名称:2-甲基-3-羟基喹啉-4-羧酸 Cas号:117-57-7 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:张经理 电话:027-59308705 手机:18827031272
QQ: 2241752642
微信二维码
电话: 19906633110