C.I.颜料红4

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品

C.I.颜料红4 基本信息

中文名称:
C.I.颜料红4 
中文别名:
颜料红4;
颜料红 4;
永固银朱R;
1-(2-氯-4-硝基苯基偶氮)-2-萘酚 
英文名称:
2-Naphthalenol,1-[2-(2-chloro-4-nitrophenyl)diazenyl]-
英文别名:
Pigment Red 4;
1-[(2-chloro-4-nitrophenyl)azo]-2-naphthalenol;
redno.228;
flametones;
blazingred;
AKA228;
RED 36;
Permanent Red 2B;
(2-Chlor-4-nitro-benzol)-(1 azo 1)-naphthol-(2);
1-(2-chloro-4-nitro-1-phenylazo)-2-hydroxynaphthalene;
Red 48;
2-Napthol;
1-(2-chloro-4-nitro-phenylazo)-[2]naphthol;
1-(2-Chlor-4-nitro-phenylazo)-[2]naphthol;
1-(2-Chlor-4-nitro-phenlazo)-naphthol-(2);
PigMent Red 4;
CRED36 
CAS No.:
2814-77-9
分 子 式:
C16H10ClN3O3
分 子 量:
327.73
精确分子量:
327.04100
PSA:
90.77000
MDL:
MFCD00037879
EINECS:
220-558-0
InChI:
InChI=1/C16H10ClN3O3/c17-13-9-11(20(22)23)6-7-14(13)18-19-16-12-4-2-1-3-10(12)5-8-15(16)21/h1-9,21H/b19-18+
危险品标志:
 
风险术语:
 
安全术语:
 
分子结构式:
SDS:
查看

C.I.颜料红4 制备方法及用途

制备方法

邻氯对硝基苯胺与盐酸、水搅拌过夜,次日液面下加入亚硝酸钠溶液重氮化,过滤,备用;2-萘酚溶于氢氧化钠溶液中,再加盐酸析出2-萘酚沉淀,显酸性;液面下加入重氮盐溶液进行偶合,反应完毕,加热,过滤,水洗,干燥,得产品。

合成制备方法

该产品通过邻氯对硝基苯胺重氮化并与α-萘酚偶合制备。

用途简介

给出黄光红色,介于更黄光的C.I颜料橙5与更蓝光的C.I.颜料红3之间色调,耐光牢度为6级,但暴晒后变暗.主要应用于空气自干型印墨,在烘焙磁漆中渗色;在胶版及包装印墨中着色强度高于颜料橙5及颜料红3,亦可用于鞋油、地板蜡、彩色粉笔、水彩及食品颜料红36(USA)。

用途

1.      主要用于油墨、水彩或油彩颜料和印泥的着色,也可用于橡胶、天然生漆、化妆品涂料和涂料印花的着色。

 

C.I.颜料红4 物化性质

外观与性状:
浅澄色的粉红色粉末
密度:
1.45 g/cm3
熔点:
276ºC
沸点:
496.7ºC at 760 mmHg
闪点:
254.2ºC
折射率:
1.684
蒸汽压:
4.25E-13mmHg at 25°C
存储条件/存储方法:
库房低温,通风,干燥
稳定性相关:

橙红色粉末,密度1.45~1.65g/cm3,着色鲜艳,不溶于水,微溶于乙醇,丙酮和苯中。溶于浓硫酸中为蓝光品红色,稀释后呈黄光红色沉淀,溶于浓硝酸中为艳朱红色,在稀氢氧化钠中不变色,流动性和遮盖性好,耐热性较差。

其它信息:

1.       性状:橙红色粉末

2.       密度(g/mL,25/4℃):1.45~1.65

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):无可用

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:不溶于水,微溶于乙醇,丙酮和苯中。

C.I.颜料红4 安全信息

海关代码:
2928000090
RTECS号:
QL3436000

C.I.颜料红4 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QL3436000
CHEMICAL NAME :
2-Naphthol, 1-((2-chloro-4-nitrophenyl)azo)-
CAS REGISTRY NUMBER :
2814-77-9
BEILSTEIN REFERENCE NO. :
0930971
LAST UPDATED :
199701
DATA ITEMS CITED :
6
MOLECULAR FORMULA :
C16-H10-Cl-N3-O3
MOLECULAR WEIGHT :
327.74
WISWESSER LINE NOTATION :
L66J BNUNR BG DNW& CQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
5 ug/plate
REFERENCE :
ESKGA2 Eisei Kagaku. Hygienic Chemistry. (Nippon Yakugakkai, 2-12-15 Shibuya, Shibuya-ku, Tokyo 150, Japan) V.1- 1953- Volume(issue)/page/year: 29,212,1983 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M2108 No. of Facilities: 1556 (estimated) No. of Industries: 16 No. of Occupations: 16 No. of Employees: 11138 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M2108 No. of Facilities: 1733 (estimated) No. of Industries: 10 No. of Occupations: 18 No. of Employees: 16211 (estimated) No. of Female Employees: 2518 (estimated)
生态数据:

该物质对环境可能有危害,对水体应给予特别注意。

C.I.颜料红4 MSDS

  Pigment Red 4      Revision number: 5    
  SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        Pigment Red 4    
    
  Revision number:        5    

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS        Not classified    
    Not classified
  HEALTH HAZARDS
  ENVIRONMENTAL HAZARDS        Not classified    
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols        None    
    No signal word
  Signal word
  Hazard statements        None    
    None
  Precautionary statements:

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance    
  Components:        Pigment Red 4    
  Percent:        ....    
  CAS Number:        2814-77-9    
  Synonyms:        Permanent Red 2B    
  Chemical Formula:        C16H10ClN3O3    

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.    
    Get medical advice/attention if you feel unwell.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Rinse skin with    
    water/shower. If skin irritation or rash occurs: Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present    
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Get medical advice/attention if you feel unwell. Rinse mouth.    
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-    
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.    
  media:
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
  from the chemical:        generate poisonous fume.    
  Pigment Red 4

Section 5. FIRE-FIGHTING MEASURES
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.    
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
    Use personal protective equipment. Keep people away from and upwind of spill/leak.
  Personal precautions,
  protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
  emergency procedures: roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
  containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
  up: appropriate laws and regulations.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
    Handling is performed in a well ventilated place. Wear suitable protective equipment.
  Technical measures:
    Prevent dispersion of dust. Wash hands and face thoroughly after handling.
    Use a local exhaust if dust or aerosol will be generated.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.    
    Store away from incompatible materials such as oxidizing agents.
  Packaging material:        Comply with laws.    

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
    Install a closed system or local exhaust as possible so that workers should not be
  Engineering controls:
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Dust respirator. Follow local and national regulations.
  Hand protection:        Protective gloves.    
  Eye protection:        Safety glasses. A face-shield, if the situation requires.    
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Solid    
  Form:        Crystal- Powder    
  Colour:        Reddish yellow - Deep yellow red    
  Odour:        No data available    
  pH: No data available
  Melting point/freezing point:No data available
    No data available
  Boiling point/range:
  Flash point:        No data available    
  Flammability or explosive
  limits:
    No data available
  Lower:
  Upper:        No data available    
    No data available
  Relative density:
  Solubility(ies):
    No data available
  [Water]
  [Other solvents]        No data available    
  Pigment Red 4

Section 10. STABILITY AND REACTIVITY
  Chemical stability:        Stable under proper conditions.    
  Possibility of hazardous No special reactivity has been reported.
  reactions:
  Incompatible materials: Oxidizing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx), Hydrogen chloride
  products:

Section 11. TOXICOLOGICAL INFORMATION
    No data available
  Acute Toxicity:
  Skin corrosion/irritation: No data available
    No data available
  Serious eye
  damage/irritation:
  Germ cell mutagenicity: mmo-sat 100 ug/plate (+S9)
    mmo-sat 5 ug/plate (-S9)
  Carcinogenicity:
  IARC =        No data available    
    No data available
  NTP =
  Reproductive toxicity:        No data available    
    QL3436000
  RTECS Number:

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available    
  Crustacea:        No data available    
  Algae:        No data available    
  Persistence / degradability: No data available
  Bioaccumulative        No data available    
  potential(BCF):
  Mobility in soil
  Log Pow:        No data available    
  Soil adsorption (Koc):        No data available    
  Henry's Law        No data available    
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
    Observe all federal, state and local regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        Does not correspond to the classification standard of the United Nations    
  UN-No:        Not listed    

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.
  Pigment Red 4


SECTION 16 - ADDITIONAL INFORMATION
N/A

C.I.颜料红4 海关数据

中国海关编码:2928000090

概述:
2928000090 其他肼(联氨)及胲(羟胺)的有机衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:20.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

C.I.颜料红4 分子结构与计算化学数据

分子结构数据

1、   摩尔折射率:85.85

2、   摩尔体积(cm3/mol):226.0

3、   等张比容(90.2K):627.2

4、   表面张力(dyne/cm):59.3

5、   极化率(10-24cm3):34.03

计算化学数据

1、   疏水参数计算参考值(XlogP):4.1

2、   氢键供体数量:1

3、   氢键受体数量:5

4、   可旋转化学键数量:2

5、   拓扑分子极性表面积(TPSA):84.6

6、   重原子数量:23

7、   表面电荷:0

8、   复杂度:543

9、   同位素原子数量:0

10、   确定原子立构中心数量:0

11、   不确定原子立构中心数量:0

12、   确定化学键立构中心数量:1

13、   不确定化学键立构中心数量:0

14、   共价键单元数量:1

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