平平加O

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

平平加O 基本信息

中文名称:
平平加O 
中文别名:
月桂醇聚氧乙烯醚;
平平加O-20;
聚氧乙烯月桂醚;
四聚乙二醇单月桂醚;
月桂醇聚;
聚乙二醇单十二烷醚 
英文名称:
peregal O
英文别名:
Polyoxyethylene lauryl ether;
ped;
la7;
polyoxethyleneglycol-23 lauryl ether;
do9;
g3711;
bl9ex;
depeg;
g3707;
yx500;
AEO4;
Polidocanol (PEG Monododecyl Ether);
bl9 
CAS No.:
9002-92-0
分 子 式:
C20H42O5
分 子 量:
1199.57
精确分子量:
1198.80000
PSA:
232.52000
MDL:
MFCD00080891
EINECS:
500-002-6
InChI:
InChI=1/C58H118O24/c1-2-3-4-5-6-7-8-9-10-11-13-60-15-17-62-19-21-64-23-25-66-27-29-68-31-33-70-35-37-72-39-41-74-43-45-76-47-49-78-51-53-80-55-57-82-58-56-81-54-52-79-50-48-77-46-44-75-42-40-73-38-36-71-34-32-69-30-28-67-26-24-65-22-20-63-18-16-61-14-12-5
危险品标志:
风险术语:
R22;R36/37/38;
安全术语:
S26;S37/39;
分子结构式:
SDS:
查看

平平加O 制备方法及用途

制备方法

1.1 mol C12~18脂肪醇在固碱催化下与20 mol环氧乙烷缩合。反应在管式反应器中进行。反应器的前部分为264根5.5 m长、16 mm口径的钢管,后部分为58根长5.5 m、25.4 mm的钢管组成。各管间用U形环连成串联形式。其中16 mm的管共长1 448 mm,25.4 mm管共长318 mm。16 mm管的前部为预热区,其余部分为反应区,25.4 mm的管全部为浸渍区。全部管放在一个密封的水槽中。通过管和控制器维持进入水槽中一定数量的热水,反应室内的温度维持在120~140℃。此温度由压力控制调节器控制。水槽一端的盖上有许多环氧乙烷进料口,进料口与环氧乙烷贮罐相连。具体操作是将固体催化剂加入供料罐中,熔化的脂肪醇用泵打入供料罐中,两种原料在供料罐中混匀后打入反应室的预热部分。当温度升至50~70℃时,环氧乙烷从贮罐压入各加料口进入反应室。经取料测浊点(1%水溶液)达到75℃左右反应终止。反应液进入中和釜,用冰醋酸调pH值至5.0~7.0,然后加入双氧水漂白脱色,冷却到50℃以下,放料包装即为成品。

合成制备方法

1.1 mol C1218脂肪醇在固碱催化下与20 mol环氧乙烷缩合。反应在管式反应器中进行。反应器的前部分为264根5.5 m长、16 mm口径的钢管,后部分为58根长5.5 m、25.4 mm的钢管组成。各管间用U形环连成串联形式。其中16 mm的管共长1 448 mm,25.4 mm管共长318 mm。16 mm管的前部为预热区,其余部分为反应区,25.4 mm的管全部为浸渍区。全部管放在一个密封的水槽中。通过管和控制器维持进入水槽中一定数量的热水,反应室内的温度维持在120~140℃。此温度由压力控制调节器控制。水槽一端的盖上有许多环氧乙烷进料口,进料口与环氧乙烷贮罐相连。
具体操作是将固体催化剂加入供料罐中,熔化的脂肪醇用泵打入供料罐中,两种原料在供料罐中混匀后打入反应室的预热部分。当温度升至50~70℃时,环氧乙烷从贮罐压入各加料口进入反应室。经取料测浊点(1%水溶液)达到75℃左右反应终止。反应液进入中和釜,用冰醋酸调pH值至5.0~7.0,然后加入双氧水漂白脱色,冷却到50℃以下,放料包装即为成品。

用途简介

1、MOA-3、MOA-4、MOA-5易溶于油及极性溶剂中,水中呈扩散状,具有良好的乳化性能,作w/o型乳化剂,用于矿物油、脂族溶剂的乳化,聚氯乙烯塑料溶胶的降粘剂,在化纤油剂中广泛使用,MOA-3是生产AES的主要原料,MOA-4可作硅酮和烃类的乳化剂、干洗剂。2、MOA-7、MOA-9易溶于水,具有优良的乳化、净洗、润湿性能,在毛纺工业中作羊毛净洗剂及脱脂剂、织物的精练剂、净洗剂;可作为液体洗涤剂的重要组成部分;在化妆品和软膏生产中作乳化剂;对矿物油和动、植物油脂均有极好的乳化、分散、润湿性能;还可作为玻璃纤维抽丝油剂的乳化剂。3、MOA-15、MOA-20、MOA-23作羊毛脱脂剂、织物净洗剂、液体洗涤剂、烃类溶剂及一般工业乳化剂、香精油增溶剂、抗静电剂的润湿剂、电渡工业中的光亮剂。MOA-20在印染工业中做为匀染剂,效果显著,且具有良好的煮练性能,在染色工业中加该助剂不但能达到缓染、匀染的目的,同时还能增强染色坚牢度,着色鲜艳、美观。

用途

1.用作匀染剂,如作直接、还原、酸性、分散、阳离子染料染色的匀染剂。用于直接染料染色时用量0.2~1 g/L。用作扩散剂可防止某些冰染染料显色时的分解物粘连在织物上而造成污染,并可减少显色横棍轴上的积垢。亦可用作剥色剂、印花防染剂,色泽的深浅按平平加O用量而变化。一般用量为5~10 g/L。还可用作防白助剂,蓝色基BB增艳剂,原毛净洗剂,活性染料印花净洗剂,静电防止剂及乳化剂。作剥色剂一般用量0.2~1 g/L.。

2.用作羊毛脱脂剂、织物净洗剂、家用洗净剂活性物及一般工业乳化剂。

平平加O 物化性质

外观与性状:
透明油性液体
密度:
0.99 g/mL±0.002 g/mL at 20 °C
熔点:
41-45 °C(lit.)
沸点:
100 °C(lit.)
闪点:
>230 °F
水溶解性:
可溶
折射率:
n20/D 1.461
存储条件/存储方法:

常温密闭,避光,通风干燥处

稳定性相关:

常温常压下稳定

避免光,明火,高温

其它信息:

1.       性状:白色膏状流体

2.       密度(g/mL,20℃): 0.950-0.965

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):41-45

5.       沸点(ºC,常压):100

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:1.461

8.       闪点(ºC): 190

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):>110

11.    蒸气压(kPa,25ºC):0.133

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:溶于水溶解度为:40 mg/mL at 20 °C

 

平平加O 安全信息

海关代码:
34021300
WGK_Germany:
3
德国有关水污染物质的分类清单
危险类别码:
R22;R36/37/38
安全说明:
26-39-37/39-36/37/39-36-24/25
RTECS号:
MD0875000
危险标志:
Xn:Harmful

平平加O 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
JR5990000
CHEMICAL NAME :
Dodecyl alcohol condensed with 23 moles ethylene oxide
CAS REGISTRY NUMBER :
9002-92-0
LAST UPDATED :
199710
DATA ITEMS CITED :
6
WISWESSER LINE NOTATION :
T3OTJ 23 &Q12

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
8600 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
SPCOAH Soap, Perfumery & Cosmetics. (London, UK) V.8(7)-48(2), 1935-75. Volume(issue)/page/year: 38,47,1965
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
3500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
APRCAS American Perfumer and Cosmetics. (Oak Park, IL) V.77-86, 1962-71. For publisher information, see CSPEAX. Volume(issue)/page/year: 77,35,1962 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - A1179 No. of Facilities: 3288 (estimated) No. of Industries: 33 No. of Occupations: 37 No. of Employees: 43764 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - A1179 No. of Facilities: 5821 (estimated) No. of Industries: 32 No. of Occupations: 40 No. of Employees: 104035 (estimated) No. of Female Employees: 60645 (estimated)
毒理学数据:

急性毒性:

大鼠经口LD50: 8600 mg/kg;

大鼠皮下LD50: 954 mg/kg

大鼠注射LD50: 27 mg/kg;

小鼠经口LC50: 4940 mg/kg

小鼠腹腔LC50: 160 mg/kg;

小鼠皮下LC50: 192 mg/ kg

小鼠注射LC50: 100 mg/kg;

生态数据:

通常对水是稍微危害的,不要将未稀释或大量产品接触地下水,水道或者污水系统。若无政府许可,勿将材料排入周围环境。

平平加O MSDS

Name: BRIJ 35 30% w/v solution in water Material Safety Data Sheet
Synonym: None Known
CAS: 9002-92-0
Section 1 - Chemical Product   MSDS Name:BRIJ 35 30% w/v solution in water Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
9002-92-0 BRIJ 35, 30% w/v solution in water unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 9002-92-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear
Odor: Not available.
pH: 5-7
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 235 deg F ( 112.78 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 1.03
Molecular Formula: Solution
Molecular Weight: 0

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 9002-92-0: JR5960000 JR5970000 JR5990000 MD0875000 LD50/LC50:
CAS# 9002-92-0: Draize test, rabbit, eye: 10 mg; Draize test, rabbit, eye: 100 mg; Draize test, rabbit, eye: 750 ug/24H Severe; Draize test, rabbit, skin: 100 mg; Draize test, rabbit, skin: 500 mg/24H Mild; Draize test, rabbit, skin: 75 mg/24H Mild; Draize test, rabbit, skin: 500 mg/24H Moderate; Oral, mouse: LD50 = 4940 mg/kg; Oral, mouse: LD50 = 1170 mg/kg; Oral, mouse: LD50 = 3500 mg/kg; Oral, mouse: LD50 = 1170 mg/kg; Oral, rat: LD50 = 8600 mg/kg; Oral, rat: LD50 = 4150 mg/kg; Oral, rat: LD50 = 8600 mg/kg; Oral, rat: LD50 = 1 gm/kg.
Carcinogenicity:
BRIJ 35, 30% w/v solution in water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 9002-92-0: 2
Canada
CAS# 9002-92-0 is listed on Canada's DSL List.
CAS# 9002-92-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 9002-92-0 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

平平加O 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:1

3.氢键受体数量:2

4.可旋转化学键数量:13

5.互变异构体数量:无

6.拓扑分子极性表面积29.5

7.重原子数量:16

8.表面电荷:0

9.复杂度:115

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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产品名称:月桂醇聚氧乙烯醚 Cas号:9002-92-0 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
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联系人:彭 电话:027-59223108 手机:15107166787