磷酸脲

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学
  • 上游产品
  • 下游产品
  • 表征图谱

磷酸脲 基本信息

中文名称:
磷酸脲 
中文别名:
尿素 磷酸盐;
磷酸脲 
英文名称:
urea phosphate
英文别名:
Urea phosphate;
urea dihydrogenphosphate;
CARBAMIDE PHOSPHATE;
Urea PhosphateUP;
urea,acidic phosphate;
Urea-phosphoricacid;
urea trihydrophosphate;
Harnstoffphosphat;
Urea orthophosphate 
CAS No.:
4861-19-2
分 子 式:

CO(NH2)2·H3PO4

分 子 量:
158.05
精确分子量:
158.00900
PSA:
156.68000
MDL:
MFCD00012602
EINECS:
225-464-3
BRN:
3709707
InChI:
InChI=1/CH4N2O.H3O4P/c2-1(3)4;1-5(2,3)4/h(H4,2,3,4);(H3,1,2,3,4)
危险品标志:

 

风险术语:

S22;S24/25

安全术语:

S22;S24/25;

分子结构式:
SDS:
查看

磷酸脲 制备方法及用途

制备方法

二次结晶法

合成制备方法

二次结晶法

用途简介

磷酸脲是一种优良的饲料添加剂,它为性畜提供磷和非蛋白氮(尿素态氮)两种营养元素,安全性比尿素高。它还是一种高浓度氮磷复合肥料(总养分元素61%),适用于碱性土壤。除用作饲料、肥料外,还可以作阻燃剂,金属表面处理剂、发酵营养剂、清洗剂及净化磷酸用助剂等。

用途

是优良的饲料添加剂,可为牲畜提供磷和非蛋白氮(尿素态氮)两种营养元素,特别适用于反刍动物饲用,能减缓牛、羊瘤胃和血中氮的释放和传递速度,安全性比尿素高。也是一种高浓度氮磷复合肥料,适于碱性土壤,对水稻、小麦、油菜等作物均有增产效果。还用作阻燃剂、金属表面处理剂、发酵营养剂、清洗剂和净化磷酸用助剂。

磷酸脲 物化性质

熔点:
116-118 °C (dec.)(lit.)
沸点:
158ºC at 760 mmHg
闪点:
311.2ºC
水溶解性:
50 mg/mL
存储条件/存储方法:

应贮存在阴凉、通风、干燥的库房中。

稳定性相关:

易溶于水,其水溶液呈酸性,1%水溶液的pH值为1.89;不溶于醚类、甲苯、四氯化碳和二烷中。

失火时,可用水、砂土和二氧化碳灭火器扑救。

其它信息:

1.       性状:无色透明棱柱状晶体。

磷酸脲 安全信息

海关代码:
3105590000
WGK_Germany:
1
德国有关水污染物质的分类清单
安全说明:
S22-S24/25
安全标志:
S22:不要吸入粉尘。
S24/25:防止皮肤和眼睛接触。

磷酸脲 毒理性

生态数据:

通常对水是不危害的,若无政府许可,勿将材料排入周围环境

磷酸脲 MSDS


Section 1. Chemical Product and Company Identification
    Urea Phosphate
    Common Name/
    Trade Name
    Manufacturer
    Commercial Name(s)
    Synonym
    Chemical Name
    Chemical Family
    Urea Phosphate

Section 4. First Aid Measures
    Eye Contact        Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at    
    least 15 minutes. Get medical attention if irritation occurs.
    Skin Contact        Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.    
    Serious Skin Contact        Not available.    
    Inhalation        If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get    
    medical attention.
    Serious Inhalation        Not available.    
    Ingestion        Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an    
    unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
    clothing such as a collar, tie, belt or waistband.
    Serious Ingestion        Not available.    

Section 5. Fire and Explosion Data
    Flammability of the Product May be combustible at high temperature.
    Auto-Ignition Temperature Not available.
    Flash Points        Not available.    
    Flammable Limits        Not available.    
    Products of Combustion        These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), phosphates.    
    Fire Hazards in Presence of Slightly flammable to flammable in presence of heat.
    Various Substances
    Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
    Risks of explosion of the product in presence of static discharge: Not available.
    of Various Substances
    SMALL FIRE: Use DRY chemical powder.
    Fire Fighting Media
    and Instructions        LARGE FIRE: Use water spray, fog or foam. Do not use water jet.    
    As with most organic solids, fire is possible at elevated temperatures
    Special Remarks on
    Fire Hazards
    Special Remarks on Explosion Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust
    Hazards        explosion hazard.    

Section 6. Accidental Release Measures
    Small Spill        Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by    
    spreading water on the contaminated surface and dispose of according to local and regional authority
    requirements.
    Large Spill        Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water    
    on the contaminated surface and allow to evacuate through the sanitary system.
    Urea Phosphate

Section 7. Handling and Storage
    Precautions        Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not    
    breathe dust. Keep away from incompatibles such as oxidizing agents.
    Storage        Keep container tightly closed. Keep container in a cool, well-ventilated area.    

Section 8. Exposure Controls/Personal Protection
    Engineering Controls        Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below    
    recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
    airborne contaminants below the exposure limit.
    Personal Protection
    Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Use a
    dust respirator if ventilation is inadequate and dust is visible. Gloves.
    Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
    a Large Spill        to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist    
    BEFORE handling this product.
    Exposure Limits        Not available.    

Section 9. Physical and Chemical Properties
    Physical state and appearance Solid. (Crystalline solid.)        Odor        Not available.    
    Taste        Not available.    
    Molecular Weight        158.05 g/mole    
    Color        Not available.    
    pH (1% soln/water)        Not available.    
    Boiling Point        Not available.    
    Melting Point        116°C (240.8°F)    
    Critical Temperature        Not available.    
    Not available.
    Specific Gravity
    Vapor Pressure        Not applicable.    
    Vapor Density        Not available.    
    Volatility        Not available.    
    Odor Threshold        Not available.    
    Not available.
    Water/Oil Dist. Coeff.
    Ionicity (in Water)        Not available.    
    Not available.
    Dispersion Properties
    Solubility        Not available.    

Section 10. Stability and Reactivity Data
    Stability        The product is stable.    
    Not available.
    Instability Temperature
    Conditions of Instability        Excess heat, incompatible materials, dust generation    
    Incompatibility with various        Reactive with oxidizing agents.    
    substances
    Corrosivity        Not available.    
    Urea Phosphate
    Special Remarks on        Not available.    
    Reactivity
    Special Remarks on        Not available.    
    Corrosivity
    Polymerization        Will not occur.    

Section 11. Toxicological Information
    Routes of Entry        Inhalation. Ingestion.    
    Toxicity to Animals        LD50: Not available.    
    LC50: Not available.
    Chronic Effects on Humans Not available.
    Other Toxic Effects on        Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.    
    Humans
    Special Remarks on        Not available.    
    Toxicity to Animals
    Special Remarks on
    Not available.
    Chronic Effects on Humans
    Special Remarks on other        Acute Potential Health Effects:    
    Toxic Effects on Humans        Skin: May cause skin irritation.    
    Eyes: Dust may cause eye irritation.
    Inhalation: Dust may cause respiratory tract irritation.
    Ingestion: Expected to be a low hazard for usual industrial handling. The toxicological properties of this
    substance have not been fully investigated.

Section 12. Ecological Information
    Ecotoxicity        Not available.    
    BOD5 and COD        Not available.    
    Products of Biodegradation        Possibly hazardous short term degradation products are not likely. However, long term degradation products may    
    arise.
    Toxicity of the Products        The product itself and its products of degradation are not toxic.    
    of Biodegradation
    Special Remarks on the        Not available.    
    Products of Biodegradation

Section 13. Disposal Considerations
    Waste Disposal        Waste must be disposed of in accordance with federal, state and local environmental    
    control regulations.

Section 14. Transport Information
    DOT Classification        Not a DOT controlled material (United States).    
    Identification        Not applicable.    
    Not applicable.
    Special Provisions for
    Transport
    Urea Phosphate
    DOT (Pictograms)

Section 15. Other Regulatory Information and Pictograms
    No products were found.
    Federal and State
    Regulations
    California        California prop. 65: This product contains the following ingredients for which the State of California has found    
    to cause cancer which would require a warning under the statute: No products were found.
    Proposition 65
    Warnings
    California prop. 65: This product contains the following ingredients for which the State of California has found
    to cause birth defects which would require a warning under the statute: No products were found.
    Other Regulations        Not available.    
    WHMIS (Canada) Not controlled under WHMIS (Canada).
    Other Classifications
    DSCL (EEC)        This product is not classified according S22- Do not breathe dust.    
    to the EU regulations.        S24/25- Avoid contact with skin and eyes.    
    Health Hazard
    HMIS (U.S.A.)        1 National Fire Protection    
    1 Flammability
    1 Association (U.S.A.)
    Fire Hazard
    1 0 Reactivity
    Health
    Reactivity
    0
    Specific hazard
    Personal Protection
    E
    WHMIS (Canada)
    (Pictograms)
    DSCL (Europe)
    (Pictograms)
    TDG (Canada)
    (Pictograms)
    ADR (Europe)
    (Pictograms)
    Protective Equipment
    Gloves.
    Lab coat.
    Dust respirator. Be sure to use an
    approved/certified respirator or
    equivalent.
    Urea Phosphate


SECTION 16 - ADDITIONAL INFORMATION
N/A

磷酸脲 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:5

3.氢键受体数量:5

4.可旋转化学键数量:0

5.互变异构体数量:2

6.拓扑分子极性表面积147

7.重原子数量:9

8.表面电荷:0

9.复杂度:78.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:2

磷酸脲 上游产品

磷酸脲 下游产品

推荐供应商更多供应商>>

湖北云镁科技有限公司

产品介绍:
产品名称:磷酸脲 Cas号:4861-19-2 纯度:99% 包装信息:349kg,1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶 价格:1.0元 - 349.0元
联系方式:
联系人:方经理 电话:027-59206672 手机:18327059871

湖北诺纳科技有限公司

产品介绍:
产品名称:磷酸脲 Cas号:4861-19-2 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶 价格:1.0元 - 25.0元
联系方式:
联系人:邵经理 电话:027-59209883 手机:17386169806

湖北巨胜科技有限公司

产品介绍:
产品名称:磷酸脲厂家 Cas号:4861-19-2 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:孙敏 电话:027-59599240 手机:18702754003

湖北垚烁泉化工有限公司

产品介绍:
产品名称:磷酸脲 Cas号:4861-19-2 纯度:98% 包装信息:1kg,25kg 价格:10.0元 - 100.0元
联系方式:
联系人:吴 电话:18971238634 手机:18971238634

武汉鑫伟烨化工有限公司

产品介绍:
产品名称:磷酸脲 Cas号:4861-19-2 纯度:98% 包装信息:25kg,25kg,25kg 价格:1.0元 - 1.0元
联系方式:
联系人:郭经理 电话:027-85953558 手机:13377862267

云南力莲生物有限公司

产品介绍:
产品名称:磷酸脲 Cas号:4861-19-2 纯度:99% 包装信息:25桶kg 价格:9.0元
联系方式:
联系人:彭强 电话:19912838225 手机:19912830060

武汉富鑫远科技有限公司

产品介绍:
产品名称:磷酸脲 Cas号:4861-19-2 纯度:99% 包装信息:1kg袋,25kg袋,1000kg袋 价格:洽谈
联系方式:
联系人:郑先生 电话:18971353902 手机:18971353902

湖北鑫鸣泰化学有限公司

产品介绍:
产品名称:磷酸脲 Cas号:4861-19-2 纯度:99% 包装信息:100kg,200kg 价格:1.0元 - 1.0元
联系方式:
联系人:黄 电话:027-50662354 手机:13264726139

湖北鑫鸣泰化学有限公司

产品介绍:
产品名称:磷酸脲 Cas号:4861-19-2 纯度:98% 包装信息:25/桶kg 价格:1.0元
联系方式:
联系人:黄经理 电话:027-51833411 手机:13237166274

湖北万得化工有限公司

产品介绍:
产品名称:磷酸脲 Cas号:4861-19-2 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶,200kg镀锌铁桶/塑料桶,1t吨袋 价格:1.0元 - 1,000.0元
联系方式:
联系人:库薇 电话:027-59210159 手机:15172311821